10177-79-4

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10177-79-4 Structure

Identification	Back Directory
[Name] BIS(2-METHOXYPHENYL)PHOSPHINE
[CAS] 10177-79-4
[Synonyms] Di-o-anisylphosphine BIS(2-METHOXYPHENYL)PHOSPHIN BIS(2-METHOXYPHENYL)PHOSPHINE bis(2-methoxyphenyl)phosphane Phosphine,bis(2-methoxyphenyl)-
[Molecular Formula] C14H15O2P
[MDL Number] MFCD08064038
[MOL File] 10177-79-4.mol
[Molecular Weight] 246.24

Chemical Properties	Back Directory
[Melting point ] 86-90°C
[Boiling point ] 368.2±42.0 °C(Predicted)
[form ] powder
[InChI] 1S/C14H15O2P/c1-15-11-7-3-5-9-13(11)17-14-10-6-4-8-12(14)16-2/h3-10,17H,1-2H3
[InChIKey] HFEAMIKDDWKNAG-UHFFFAOYSA-N
[SMILES] COc1ccccc1Pc2ccccc2OC

Safety Data	Back Directory
[Symbol(GHS) ] GHS02,GHS07
[Signal word ] Warning
[Hazard statements ] H228-H315-H319-H335
[Precautionary statements ] P210-P302+P352-P305+P351+P338
[Hazard Codes ] F,Xi
[Risk Statements ] 11-36/37/38
[Safety Statements ] 26
[RIDADR ] UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
[WGK Germany ] 3
[Storage Class] 4.1B - Flammable solid hazardous materials
[Hazard Classifications] Eye Irrit. 2 Flam. Sol. 2 Skin Irrit. 2 STOT SE 3

Hazard Information	Back Directory
[Uses] Reactant for: Allylation of phenols Synthesis of neutral rhodium(I) complexes Dinuclear Pd(II) complexes bearing bis-bidentate tetraphos ligands CO-ethylene copolymerization reactions Suzuki-Miyaura reaction for synthesis of alkyl derivatives phosphine sulfonate (P-O) ligands
[reaction suitability] reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand

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