| Identification | Back Directory | [Name]
BIS(2-FURYL)CHLOROPHOSPHINE | [CAS]
181257-35-2 | [Synonyms]
Chlorodi(2-furyl)phosphine
BIS(2-FURYL)CHLOROPHOSPHINE
chlorodi(furan-2-yl)phosphine
Bis(2-furyl)phosphine chloride,
chloro-bis(furan-2-yl)phosphane
Di-2-furanylphosphinous chloride
Chlorodi(2-furyl)phosphine, 98+%
Bis(2-furyl)phosphinechloride,98+%
Bis(2-furyl)phosphine chloride 85%
Phosphinous chloride, P,P-di-2-furanyl- | [Molecular Formula]
C8H6ClO2P | [MDL Number]
MFCD01630851 | [MOL File]
181257-35-2.mol | [Molecular Weight]
200.56 |
| Chemical Properties | Back Directory | [Boiling point ]
102-104°C/14mm | [density ]
1.287 g/mL at 25 °C | [Fp ]
102-104°C/14mm | [refractive index ]
1.5930 | [form ]
liquid | [Water Solubility ]
Reacts with water. | [Sensitive ]
Moisture Sensitive | [InChI]
1S/C8H6ClO2P/c9-12(7-3-1-5-10-7)8-4-2-6-11-8/h1-6H | [InChIKey]
IYEUYNXDXNWPJI-UHFFFAOYSA-N | [SMILES]
ClP(c1ccco1)c2ccco2 |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
14-34 | [Safety Statements ]
26-36/37/39-45 | [RIDADR ]
UN3265 | [WGK Germany ]
3 | [HazardClass ]
8 | [PackingGroup ]
II | [Storage Class]
4.3 - Hazardous materials which set free flammable gases upon contact with water | [Hazard Classifications]
Skin Corr. 1B
Water-react 2 |
| Hazard Information | Back Directory | [Uses]
Reactant for synthesis of:
- Centrostereogenic 1,3-bidentate ferrocenyldiphosphane ligands
- Ferrocene-based chiral diphosphine
- Phosphine containing amino acids
Reactant for:
- α-Arylation of aldehydes
- Stereoselective [2,3] sigmatropic rearrangement of acyclic allylic phosphinites
- Hydrophosphination of functionalized alkenes
| [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand |
|
| Company Name: |
Alfa Aesar
|
| Tel: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
|