ChemicalBook--->CAS DataBase List--->102-27-2

102-27-2

102-27-2 Structure

102-27-2 Structure
IdentificationMore
[Name]

N-Ethyl-3-methylaniline
[CAS]

102-27-2
[Synonyms]

1-(ETHYLAMINO)-3-METHYLBENZENE
3-ETHYLAMINOTOLUENE
3-METHYL-N-ETHYLANILINE
Ethylamino-3-methylbenzene
N-ETHYL-3-METHYLANILINE
N-ETHYL-3-TOLUIDINE
N-ETHYL-M-TOLUIDINE
3(ethylamino)-toluen
m-Methyl-N-ethylaniline
m-Toluidine, N-ethyl-
n-ethyl-3-methyl-benzenamin
N-Ethyl-3-methylbenzenamine
N-ethyl-3-methyl-Benzenamine
N-Ethyl-meta-toluidine
n-ethyl-m-toluidin
N-Ethyl-N-(3-methylphenyl)amine
N-Ethyltoluidine
N-Ethyl-3-aminotoluene
N-Ethyl-m-toluidine, 99+%
N-ethyl-m-methylaniline
[EINECS(EC#)]

203-019-4
[Molecular Formula]

C9H13N
[MDL Number]

MFCD00009027
[Molecular Weight]

135.21
[MOL File]

102-27-2.mol
Chemical PropertiesBack Directory
[Appearance]

clear yellowish to brown liquid
[Melting point ]

-6.87°C (estimate)
[Boiling point ]

221 °C (lit.)
[density ]

0.957 g/mL at 25 °C(lit.)
[vapor pressure ]

10.9-106Pa at 20-50℃
[refractive index ]

n20/D 1.546(lit.)
[Fp ]

89 °C
[solubility ]

soluble in Alcohol,Ether
[form ]

clear liquid
[pka]

5.27±0.25(Predicted)
[color ]

Colorless to Red to Green
[Water Solubility ]

1131 mg/L (20 ºC)
[BRN ]

742170
[Henry's Law Constant]

1.6×100 mol/(m3Pa) at 25℃, HSDB (2015)
[InChI]

1S/C9H13N/c1-3-10-9-6-4-5-8(2)7-9/h4-7,10H,3H2,1-2H3
[InChIKey]

GUYMMHOQXYZMJQ-UHFFFAOYSA-N
[SMILES]

CCNc1cccc(C)c1
[Uses]

Chemical intermediate.
[CAS DataBase Reference]

102-27-2(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzenamine, N-ethyl-3-methyl-(102-27-2)
[EPA Substance Registry System]

102-27-2(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Skull and Crossbones (GHS06)
GHS06
[Signal word ]

Danger
[Hazard statements ]

H301+H311+H331-H315-H319-H335
[Precautionary statements ]

P261-P280-P301+P310-P302+P352+P312-P304+P340+P311-P305+P351+P338
[Hazard Codes ]

T
[Risk Statements ]

R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 2754 6.1/PG 2
[WGK Germany ]

2
[RTECS ]

CY0440000
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

29214300
[Storage Class]

6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
[Hazard Classifications]

Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
[Hazardous Substances Data]

102-27-2(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Bromoethane-->m-Toluidine
[Preparation Products]

Basic Blue 11-->4-(N-Ethyl-N-2-hydroxyethyl)-2-methylphenylenediamine sulfate-->N-Chloroethyl-N-ethylaniline-->N-Ethyl-N-chloroethyl-3-toluidine-->Sodium 3-(N-ethyl-3-methylanilino)-2-hydroxypropanesulfonate-->2-(N-Ethyl-m-toluidino)ethanol
Hazard InformationBack Directory
[General Description]

A light amber liquid. Flash point 193°F. Less dense than water and insoluble in water. Vapors heavier than air. Produces toxic oxides of nitrogen during combustion. Used to make other chemicals.
[Reactivity Profile]

N-ETHYL-M-TOLUIDINE(102-27-2) neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
[Air & Water Reactions]

Insoluble in water.
[Health Hazard]

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
[Chemical Properties]

clear yellowish to brown liquid
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

N-Ethyl-3-methylaniline(102-27-2).msds
Spectrum DetailBack Directory
[Spectrum Detail]

N-Ethyl-3-methylaniline(102-27-2)MS
N-Ethyl-3-methylaniline(102-27-2)1HNMR
N-Ethyl-3-methylaniline(102-27-2)13CNMR
N-Ethyl-3-methylaniline(102-27-2)IR1
N-Ethyl-3-methylaniline(102-27-2)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

N-Ethyl-m-toluidine, 99+%(102-27-2)
[Sigma Aldrich]

102-27-2(sigmaaldrich)
[TCI AMERICA]

N-Ethyl-m-toluidine,>98.0%(GC)(102-27-2)
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