ChemicalBook--->CAS DataBase List--->102-85-2

102-85-2

102-85-2 Structure

102-85-2 Structure
IdentificationMore
[Name]

TRIBUTYL PHOSPHITE
[CAS]

102-85-2
[Synonyms]

PHOSPHOROUS ACID TRIBUTYL ESTER
PHOSPHOROUS ACID TRI-N-BUTYL ESTER
TRIBUTYL PHOSPHITE
TRI-N-BUTYL PHOSPHITE
1,1’,1’’-phosphinidynetri-1-butano
Butyl phosphite ((C4H9O)3P)
jp304
Phosphorus derivative
phosphorustributoxide(p(obu)3)
Syn-O-Ad P-312
Tributoxyphosphine
Tributylfosfit
Tributyl phsophite
TRIBUTYL PHOSPHITE, TECH., 90%
Tri-n-butylphosphite,min.94%
Tri-n-butylphosphite, min. 94%
Phosphorous acid tributyl
[EINECS(EC#)]

203-061-3
[Molecular Formula]

C12H27O3P
[MDL Number]

MFCD00009437
[Molecular Weight]

250.31
[MOL File]

102-85-2.mol
Chemical PropertiesBack Directory
[Appearance]

Clear colorless liquid
[Melting point ]

-80 °C
[Boiling point ]

125 °C
[density ]

0.925 g/mL at 25 °C(lit.)
[vapor pressure ]

3.2Pa at 20℃
[refractive index ]

n20/D 1.431(lit.)
[Fp ]

197 °F
[solubility ]

Chloroform (Sparingly), Methanol (Slightly)
[form ]

liquid
[color ]

colorless
[Specific Gravity]

0.925
[Water Solubility ]

Not miscible or difficult to mix in water.
[Sensitive ]

Air & Moisture Sensitive
[BRN ]

1703866
[InChI]

1S/C12H27O3P/c1-4-7-10-13-16(14-11-8-5-2)15-12-9-6-3/h4-12H2,1-3H3
[InChIKey]

XTTGYFREQJCEML-UHFFFAOYSA-N
[SMILES]

CCCCOP(OCCCC)OCCCC
[CAS DataBase Reference]

102-85-2(CAS DataBase Reference)
[EPA Substance Registry System]

Tributyl phosphite (102-85-2)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
[Signal word ]

Danger
[Hazard statements ]

H312-H314-H227-H303-H315-H319
[Precautionary statements ]

P280-P305+P351+P338-P310-P210e-P312a-P403+P235-P501a
[Hazard Codes ]

C
[Risk Statements ]

R21:Harmful in contact with skin.
R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3265 8/PG 3
[WGK Germany ]

3
[RTECS ]

TH0875000
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29209085
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Acute Tox. 4 Dermal
Skin Corr. 1B
[Toxicity]

LD50 oral in rat: 3gm/kg
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

tributyl phosphite(102-85-2).msds
Hazard InformationBack Directory
[Chemical Properties]

Clear colorless liquid
[Uses]

Tributyl phosphite may be employed as model lubricant additive and its surface chemistry on Fe3O4 in ultrahigh vacuum is investigated.
[Uses]

Tributyl Phosphite inhibits fluoroacetanilide poisoning in mammals.
[Uses]

Tributyl phosphite may be employed as model lubricant additive and its surface chemistry on Fe3O4 in ultrahigh vacuum is investigated.
[General Description]

Tributyl phosphite is an alkylphosphite and is reported to inhibit carboxylesterase activity.
[Purification Methods]

Fractionate the phosphite with an efficient column. It is stable in air but is slowly hydrolysed by H2O. [Gerrard J Chem Soc 1464 1940, Fertig et al. J Chem Soc 1488 1957, Fields J Am Chem Soc 80 2358 1958, Gillis et al. J Am Chem Soc 80 2999 1958, Beilstein 1 IV 1527.]
Spectrum DetailBack Directory
[Spectrum Detail]

TRIBUTYL PHOSPHITE(102-85-2)MS
TRIBUTYL PHOSPHITE(102-85-2)1HNMR
TRIBUTYL PHOSPHITE(102-85-2)13CNMR
TRIBUTYL PHOSPHITE(102-85-2)IR1
TRIBUTYL PHOSPHITE(102-85-2)IR2
TRIBUTYL PHOSPHITE(102-85-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Tributyl phosphite, 94%(102-85-2)
[Alfa Aesar]

Tri-n-butyl phosphite, 94%(102-85-2)
[Sigma Aldrich]

102-85-2(sigmaaldrich)
[TCI AMERICA]

Tributyl Phosphite,>93.0%(GC)(102-85-2)
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