| Identification | More | [Name]
(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE | [CAS]
102308-32-7 | [Synonyms]
1,1-DIMETHYLETHYL-(S)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINE CARBOXYLATE
GARNER'S ALDEHYDE
(S)-(-)-3-BOC-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE
(S)-3-BOC-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE
(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE
(S)-4-FORMYL-2,2-DIMETHYL-OXAZOLIDINE-3-CARBOXYLIC ACID TERT-BUTYL ESTER
(S)-N-BOC-2,2-DIMETHYLOXAZOLINDINE-4-CARBOXALDEHYDE
TERT-BUTYL (S)-(-)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINECARBOXYLATE
TERT-BUTYL (S)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINECARBOXYLATE
(S)-(-)-3-tert-Butoxycarbonyl-4-formyl-2,2-dimethyl
(S)-4-Formyl-2,2-dimethyl-oxazolidine-3-carboxylictert-butylester
(-)-n-boc-n,o-isopropylidene-l-serinal
(s)-(-)-3-boc-2,2-dimethyloxazolidine-4-carboxaldehyde
(s)-(-)-3-tert-butoxycarbonyl-4-formyl-2,2-
1,1-dimethylethyl-(S)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylate, 95 %
(S)-tert-butyl 4-formyl-2,2-dimethyloxazolidine-3-carboxylate
Garners aldehyde, (-)-N-Boc-N,O-isopropylidene-L-serinal, tert-Butyl (S)-(-)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylate
(4S)-2,2-Dimethyl-3-(tert-butoxycarbonyl)oxazolidine-4-carbaldehyde
(4S)-2,2-Dimethyl-4α-formyl-3-oxazolidinecarboxylic acid tert-butyl ester
(4S)-3-(tert-Butoxycarbonyl)-2,2-dimethyl-1,3-oxazolidine-4-carbaldehyde | [Molecular Formula]
C11H19NO4 | [MDL Number]
MFCD00209557 | [Molecular Weight]
229.27 | [MOL File]
102308-32-7.mol |
| Questions And Answer | Back Directory | [Synthesis]
Garner aldehyde, (S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE, was prepared from L-serine via Boc protection. The synthetic reaction formula for (S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE is shown in the figure below: 
|
| Chemical Properties | Back Directory | [Appearance]
Clear colorless to yellow oil | [alpha ]
D -91.7° (c = 1.34 in CHCl3) | [Boiling point ]
83-88 °C1 mm Hg(lit.) | [density ]
1.06 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.445(lit.)
| [Fp ]
226 °F
| [storage temp. ]
Inert atmosphere,2-8°C | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Oil | [pka]
-3.26±0.60(Predicted) | [color ]
Clear colorless to yellow | [Optical Rotation]
[α]20/D 90°, c = 1 in chloroform | [Water Solubility ]
Slightly soluble in water. | [Sensitive ]
Air Sensitive | [BRN ]
3591324 | [InChI]
1S/C11H19NO4/c1-10(2,3)16-9(14)12-8(6-13)7-15-11(12,4)5/h6,8H,7H2,1-5H3/t8-/m1/s1 | [InChIKey]
PNJXYVJNOCLJLJ-MRVPVSSYSA-N | [SMILES]
[H]C(=O)[C@@H]1COC(C)(C)N1C(=O)OC(C)(C)C | [CAS DataBase Reference]
102308-32-7(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P264-P271-P280-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [HS Code ]
29349990 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
Clear colorless to yellow oil | [Uses]
Widely utilized in the asymmetric synthesis of natural products. | [Uses]
Chiral, non-racemic synthon for asymmetric synthesis of amino sugars and other nitrogen-containing targets. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|