ChemicalBook--->CAS DataBase List--->103-19-5

103-19-5

103-19-5 Structure

103-19-5 Structure
IdentificationMore
[Name]

P-TOLYL DISULFIDE
[CAS]

103-19-5
[Synonyms]

4-TOLYL DISULFIDE
CRESYL DISULFIDE
DICRESYL DISULFIDE
DI-P-TOLYL DISULFIDE
P-TOLYL DISULFIDE
1-Methyl-4-[(4-methylphenyl)disulfanyl]benzene
4,4’-dimethyldiphenyldisulphide
4-Methylphenyl disulfide
4-methylphenyldisulfide
Biodylon
Bis(4-methylphenyl) disulfide
bis(4-methylphenyl)disulfide
Bis(4-tolyl) disulfide
bis(4-tolyl)disulfide
bis(p-methylphenyl)disulfide
Bis(p-tolyl) disulfide
bis(p-tolyl)disulfide
Di(4-methylphenyl)disulfide
Di-4-tolyl disulfide
di-4-tolyldisulfide
[EINECS(EC#)]

203-087-5
[Molecular Formula]

C14H14S2
[MDL Number]

MFCD00008547
[Molecular Weight]

246.39
[MOL File]

103-19-5.mol
Chemical PropertiesBack Directory
[Appearance]

COLORLESS TO LIGHT YELLOW CRYSTALLINE SOLID
[Melting point ]

43-46 °C (lit.)
[Boiling point ]

349.4°C (rough estimate)
[density ]

1.2475 (rough estimate)
[refractive index ]

1.6210 (estimate)
[Fp ]

>230 °F
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[form ]

powder to crystal
[color ]

White to Orange to Green
[LogP]

5.400
[CAS DataBase Reference]

103-19-5(CAS DataBase Reference)
[EPA Substance Registry System]

Disulfide, bis(4-methylphenyl) (103-19-5)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN 3335
[WGK Germany ]

3
[RTECS ]

JO1526250
[TSCA ]

T
[HS Code ]

29309090
Hazard InformationBack Directory
[Chemical Properties]

COLORLESS TO LIGHT YELLOW CRYSTALLINE SOLID
[Uses]

4-Methylphenyl Disulfide can be useful in electrochemical regioselective C(sp2)-H selenylation and sulfenylation of substituted 2-amino-1,4-naphthoquinones.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 46, p. 2408, 1981 DOI: 10.1021/jo00324a046
Tetrahedron Letters, 34, p. 903, 1993 DOI: 10.1016/S0040-4039(00)77450-8
[Purification Methods]

Purify it by chromatography on alumina using hexane as eluent, then crystallise it from MeOH, and/or distil it in a vacuum. [Kice & Bowers J Am Chem Soc 84 2384 1962, Beilstein 6 H 245, 6 I 212, 6 II 400, 6 III 1432, 6 IV 3206.]
Spectrum DetailBack Directory
[Spectrum Detail]

P-TOLYL DISULFIDE(103-19-5)MS
P-TOLYL DISULFIDE(103-19-5)1HNMR
P-TOLYL DISULFIDE(103-19-5)13CNMR
P-TOLYL DISULFIDE(103-19-5)IR1
P-TOLYL DISULFIDE(103-19-5)IR2
P-TOLYL DISULFIDE(103-19-5)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

p-Tolyl disulfide, 98%(103-19-5)
[Sigma Aldrich]

103-19-5(sigmaaldrich)
[TCI AMERICA]

Di-p-tolyl Disulfide,>98.0%(GC)(103-19-5)
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