ChemicalBook--->CAS DataBase List--->10361-91-8

10361-91-8

10361-91-8 Structure

10361-91-8 Structure
IdentificationMore
[Name]

YTTERBIUM CHLORIDE
[CAS]

10361-91-8
[Synonyms]

YTTERBIUM CHLORIDE
YTTERBIUM(III) CHLORIDE
YbCl3
Yiterbium chloride
Ytterbium chloride (YbCl3)
ytterbiumchloride(ybcl3)
ytterbiumtrichloride
YtterbiumchlorideanhydrousREOwhitepowder
Ytterbium (III) chloride, anhydrous
YTTERBIUM(III) CHLORIDE, ANHYDROUS, BEAD S,-10 MESH, 99.99%
YTTERBIUM(III) CHLORIDE, ANHYDROUS, POW-DER, 99.9%
Ytterbium(Iii)Chloride,Anhydrous,99.9%
Ytterbium(III) chloride, anhydrous, 99.90%
Ytterbium(III)chloride,anhydrous(99.9%-Yb)(REO)
ytterbium(iii) chloride, ultra dry
YTTERBIUM(III) CHLORIDE, ANHYDROUS: 99.9% (REO)
Ytterbium Chloride Anhydrous
Ytterbium(III) chloride, ultra dry, 99.99% (REO)
Ytterbium(III) chloride, 35% min w/w aq. soln., 99.9% (REO)
Ytterbium(iii) chloride, 99.90%, anhydrous
[EINECS(EC#)]

233-800-5
[Molecular Formula]

Cl3Yb
[MDL Number]

MFCD00011288
[Molecular Weight]

279.4
[MOL File]

10361-91-8.mol
Chemical PropertiesBack Directory
[Appearance]

white powder
[Melting point ]

875 °C(lit.)
[density ]

1.48^3^0
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

soluble in H2O
[form ]

powder
[color ]

Off-white
[Water Solubility ]

Soluble in water.
[Crystal Structure]

AlCl3 type
[Sensitive ]

Hygroscopic
[crystal system]

Monoclinic
[Merck ]

14,10105
[Space group]

C2/m
[Lattice constant]

a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.6731.1650.63890110.4900.468
[Stability:]

hygroscopic
[InChI]

1S/3ClH.Yb/h3*1H;/q;;;+3/p-3
[InChIKey]

CKLHRQNQYIJFFX-UHFFFAOYSA-K
[SMILES]

Cl[Yb](Cl)Cl
[CAS DataBase Reference]

10361-91-8(CAS DataBase Reference)
[EPA Substance Registry System]

Ytterbium chloride (YbCl3) (10361-91-8)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

2
[RTECS ]

ZG2100000
[TSCA ]

Yes
[HS Code ]

28273985
[Storage Class]

13 - Non Combustible Solids
[Hazard Classifications]

Skin Irrit. 2
[Safety Profile]

Poison by intraperitoneal route. Mtldly toxic by ingestion. An experimental teratogen. A skin and eye irritant. When heated to SYN: YTTERBIUM TRICHLORIDE decomposition it emits toxic fumes of Cl-. See also YITERBIUM, RARE EARTHS, and CHLORIDES.
Hazard InformationBack Directory
[Chemical Properties]

Ytterbium(III) chloride (YbCl3) is a white powdery monoclinic crystals. It reacts with NiCl2 to form a very effective catalyst for the reductive dehalogenation of aryl halides. It is used in catalysis and as a NMR shift reagent in biology. It can also be used to track the digestion process in all animals.
Ytterbium(III) Chloride is a typical starting material for the production of Yb metal. It is also used a a source of Yb3+ ion for doping into laser host materials.
[Uses]

Used as laboratory reagent, optical glasses, structural ceramics, catalysts, electrical components and photo-optical material. Applied with NiCl2 to form a very effective catalyst for the reductive dehalogenation of aryl halides. Ytterbium(III) chloride is a powerful catalyst for the formation of acetals using trimethyl orthoformate and also used to track digestion in animals.
[Definition]

ChEBI: Ytterbium(III) chloride is the trichloride salt of ytterbium(III). It has a role as a NMR shift reagent. It contains a ytterbium(3+).
[Preparation]

Anhydrous ytterbium(III) chloride can be produced by the ammonium chloride route. In the first step, ytterbium oxide is heated with ammonium chloride to produce the ammonium salt of the pentachloride:
Yb2O3 + 10NH4Cl → 2(NH4)2YbCl5 + 6H2O + 6NH3
In the second step, the ammonium chloride salt is converted to the trichlorides by heating in a vacuum at 350-400°C:
(NH4)2YbCl5 → YbCl3 + 2HCl + 2NH3
[reaction suitability]

reagent type: catalyst
core: ytterbium
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Ytterbium(III) chloride, anhydrous, 99.90%(10361-91-8)
[Alfa Aesar]

Ytterbium(III) chloride, ultra dry, 99.99% (REO)(10361-91-8)
[Sigma Aldrich]

10361-91-8(sigmaaldrich)
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