ChemicalBook--->CAS DataBase List--->106268-95-5

106268-95-5

106268-95-5 Structure

106268-95-5 Structure
IdentificationBack Directory
[Name]

(2R)-(-)-GLYCIDYL 4-NITROBENZOATE
[CAS]

106268-95-5
[Synonyms]

GLYCIDYL4-NITROBENZOATE
(R)-(-)-GLYCIDYL-4-NITROBENZOATE
(2R)-(-)-GLYCIDYL 4-NITROBENZOATE
4-nitrobenzoate,(r)-oxiranemethano
(R)-(-)-Oxirane-2-methanol 4-nitrobenzoate
(2r)-(-)-(2,3-epoxypropylester)-4-nitrobenzoate
(R)-(-)-Glycidyl 4-nitrobenzoate, (R)-(-)-Oxirane-2-methanol 4-nitrobenzoate
[Molecular Formula]

C10H9NO5
[MDL Number]

MFCD00010835
[MOL File]

106268-95-5.mol
[Molecular Weight]

223.18
Chemical PropertiesBack Directory
[Melting point ]

60-62 °C
[storage temp. ]

2-8°C
[optical activity]

[α]19/D 37°, c = 1.08 in chloroform
[BRN ]

5278590
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[RTECS ]

RR0511000
[F ]

10-21
Spectrum DetailBack Directory
[Spectrum Detail]

(2R)-(-)-GLYCIDYL 4-NITROBENZOATE(106268-95-5)1HNMR
(2R)-(-)-GLYCIDYL 4-NITROBENZOATE(106268-95-5)Raman
(2R)-(-)-GLYCIDYL 4-NITROBENZOATE(106268-95-5)IR
Hazard InformationBack Directory
[Purification Methods]

Purify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.]
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