ChemicalBook--->CAS DataBase List--->110035-28-4

110035-28-4

110035-28-4 Structure

110035-28-4 Structure
IdentificationBack Directory
[Name]

Pyrazole-1,3-dimethyl-5-phenoxy-4-carboxaldehyde oxime
[CAS]

110035-28-4
[Synonyms]

Pyrazole-1,3-dimethyl-5-phenoxy-4-oxime
Pyrazole-1,3-dimethyl-5-phenoxy-4-carboxaldehyde oxime
1,3-DiMethyl-5-phenoxy-1H-pyrazole-4-carbaldehyde oxiMe
1,3-dimethyl-5-phenoxy-oxim-1H-pyrazole-4-carboxaldehyde
1,3-Dimethyl-5-phenoxy-1H-pyrazole-4-carboxaldehyde oxime
(E)-1,3-dimethyl-5-phenoxy-1H-pyrazole-4-carbaldehyde oxime
1H-Pyrazole-4-carboxaldehyde, 1,3-dimethyl-5-phenoxy-, oxime
N-[(1,3-dimethyl-5-phenoxypyrazol-4-yl)methylidene]hydroxylamine
Pyrazole-1,3-dimethyl-5-phenoxy-4-carboxaldehyde oxime 110035-28-4
[EINECS(EC#)]

1312995-182-4
[Molecular Formula]

C12H13N3O2
[MOL File]

110035-28-4.mol
[Molecular Weight]

231.25
Chemical PropertiesBack Directory
[Melting point ]

133-134 °C
[Boiling point ]

359.4±42.0 °C(Predicted)
[density ]

1.21
[storage temp. ]

2-8°C
[pka]

10.45±0.10(Predicted)
[InChI]

InChI=1S/C12H13N3O2/c1-9-11(8-13-16)12(15(2)14-9)17-10-6-4-3-5-7-10/h3-8,16H,1-2H3
[InChIKey]

AKGVMZJNWXUJBJ-UHFFFAOYSA-N
[SMILES]

N1(C)C(OC2=CC=CC=C2)=C(C=NO)C(C)=N1
[CAS DataBase Reference]

110035-28-4
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydroxylamine hydrochloride-->1,3-Dimethyl-5-phenoxy-1H-pyrazole-4-carboxaldehyde-->5-Chloro-1,3-dimethyl-1H-pyrazole-4-carbaldehyde-->Phenol-->1,3-Dimethyl-5-pyrazolone
Hazard InformationBack Directory
[Chemical Properties]

This product is white powdery solid, mp134~135℃, insoluble in water, soluble in methanol, ethanol and other organic solvents.
[Uses]

Pyrazole-1,3-dimethyl-5-phenoxy-4-carboxaldehyde oxime is an intermediate for the synthesis of the acaricide fenpyroximate.
[Synthesis]

1,3-Dimethyl-5-phenoxy-4-formylpyrazole was dissolved in methanol, and hydroxylamine hydrochloride was added, and pyrazole-1,3-dimethyl-5-phenoxy-4-carboxaldehyde oxime was finally obtained by the reaction.
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