ChemicalBook--->CAS DataBase List--->111-18-2

111-18-2

111-18-2 Structure

111-18-2 Structure
IdentificationMore
[Name]

N,N,N',N'-Tetramethyl-1,6-hexanediamine
[CAS]

111-18-2
[Synonyms]

1,6-BIS(DIMETHYLAMINO)HEXANE
3,3,4,4-TETRAMETHYLHEXANE
LUPRAGEN(R) N 500
N,N,N',N'-TETRAMETHYL-1,6-DIAMINOHEXANE
N,N,N',N'-TETRAMETHYL-1,6-HEXAMETHYLENE-DIAMINE
N,N,N',N'-TETRAMETHYL-1,6-HEXANEDIAMINE
N,N,N',N'-TETRAMETHYL HEXAMETHYLENE DIAMINE
TETRAMETHYLHEXANEDIAMINE
TMHD
TMHMDA
(H3C)2N(CH26N(CH3)2
1,6-Hexanediamine, N,N,N',N'-tetramethyl-
6-Hexanediamine,N,N,N’,N’-tetramethyl-1
Hexamethylenebis(dimethylamine)
koolizer1
minicotmhd
n,n,n’,n’-tetramethyl-6-hexanediamine
niaxcatalystc-210
tetramethyl-1,6-hexanediamine
toyocatmr
[EINECS(EC#)]

203-842-9
[Molecular Formula]

C10H24N2
[MDL Number]

MFCD00008339
[Molecular Weight]

172.31
[MOL File]

111-18-2.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to yellow liquid
[Melting point ]

-46 °C
[Boiling point ]

209-210 °C(lit.)
[density ]

0.806 g/mL at 25 °C(lit.)
[vapor pressure ]

12.4Pa at 20℃
[refractive index ]

n20/D 1.4359(lit.)
[Fp ]

165 °F
[storage temp. ]

Sealed in dry,Room Temperature
[solubility ]

miscible
[form ]

Liquid
[pka]

10.07±0.28(Predicted)
[color ]

Clear colorless to yellow
[Water Solubility ]

miscible
[LogP]

1.99 at 23℃
[CAS DataBase Reference]

111-18-2(CAS DataBase Reference)
[NIST Chemistry Reference]

(CH3)2N(CH2)6N(CH3)2(111-18-2)
[EPA Substance Registry System]

N,N,N',N'-Tetramethyl-1,6-hexanediamine (111-18-2)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Skull and Crossbones (GHS06)Environment (GHS09)
GHS05,GHS06,GHS09
[Signal word ]

Danger
[Hazard statements ]

H301+H311-H314-H330-H411
[Precautionary statements ]

P260-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
[Hazard Codes ]

T
[Risk Statements ]

R22:Harmful if swallowed.
R24:Toxic in contact with skin.
R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3390 6.1/PG 1
[WGK Germany ]

1
[RTECS ]

MO1370000
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29212900
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

N,N,N',N'-Tetramethyl-1,6-hexanediamine(111-18-2).msds
Hazard InformationBack Directory
[Chemical Properties]

clear colorless to yellow liquid
[Uses]

N,N,N'',N''-Tetramethyl-1,6-hexanediamine is used in the synthesis of fluorene containing poly(arylene ether sulfone) as anion exchange membranes for alkaline fuel cells.
[Preparation]

N,N,N',N'-Tetramethyl-1,6-hexanediamine can be made from adipodinitrile and dimethylamine or from 1,6- hexanediamine and formaldehyde.
[Flammability and Explosibility]

Notclassified
[Solubility in organics]

The amine is infinitely miscible with water, methanol, acetone, ether, and benzene, but insoluble in heptane. Because of its reactivity, CCl4 cannot be used as solvent. N,N,N',N'-Tetramethyl-1,6-hexanediamine (DETA) is hygroscopic and has a strong ammoniacal odor.
Spectrum DetailBack Directory
[Spectrum Detail]

N,N,N',N'-Tetramethyl-1,6-hexanediamine(111-18-2)MS
N,N,N',N'-Tetramethyl-1,6-hexanediamine(111-18-2)1HNMR
N,N,N',N'-Tetramethyl-1,6-hexanediamine(111-18-2)13CNMR
N,N,N',N'-Tetramethyl-1,6-hexanediamine(111-18-2)IR1
N,N,N',N'-Tetramethyl-1,6-hexanediamine(111-18-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

N,N,N',N'-Tetramethyl-1,6-hexanediamine, 99%(111-18-2)
[Sigma Aldrich]

111-18-2(sigmaaldrich)
[TCI AMERICA]

N,N,N',N'-Tetramethyl-1,6-diaminohexane,>98.0%(GC)(111-18-2)
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