| Identification | More | [Name]
TRIETHYLBROMOSILANE | [CAS]
1112-48-7 | [Synonyms]
BROMOTRIETHYL SILANE
TRIETHYLBROMOSILANE
bromotriethyl-silan | [EINECS(EC#)]
214-191-5 | [Molecular Formula]
C6H15BrSi | [MDL Number]
MFCD00000049 | [Molecular Weight]
195.17 | [MOL File]
1112-48-7.mol |
| Chemical Properties | Back Directory | [Melting point ]
-50°C | [Boiling point ]
66 °C24 mm Hg(lit.) | [density ]
1.135 g/mL at 20 °C(lit.)
| [refractive index ]
n20/D 1.456(lit.)
| [Fp ]
39°C | [form ]
liquid | [Specific Gravity]
1.14 | [Hydrolytic Sensitivity]
8: reacts rapidly with moisture, water, protic solvents | [InChI]
InChI=1S/C6H15BrSi/c1-4-8(7,5-2)6-3/h4-6H2,1-3H3 | [InChIKey]
UCKORWKZRPKRQE-UHFFFAOYSA-N | [SMILES]
[Si](Br)(CC)(CC)CC | [CAS DataBase Reference]
1112-48-7(CAS DataBase Reference) | [EPA Substance Registry System]
Silane, bromotriethyl- (1112-48-7) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R10:Flammable.
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2920 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [TSCA ]
Yes | [HS Code ]
2931.90.9010 |
| Hazard Information | Back Directory | [Uses]
Triethylbromosilane can be used as a protecting group for reactive hydrogens in alcohols, amines,
thiols, and carboxylic acids. Organosilanes are hydrogen-like, can be
introduced in high yield, and can be removed under selective conditions. | [Application]
Triethylbromosilane can forms silylated derivatives of alcohols stable to Grignard conditions. | [Reactions]
reacts rapidly with moisture, water, protic solvents |
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