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1112-48-7

1112-48-7 Structure

1112-48-7 Structure
IdentificationMore
[Name]

TRIETHYLBROMOSILANE
[CAS]

1112-48-7
[Synonyms]

BROMOTRIETHYL SILANE
TRIETHYLBROMOSILANE
bromotriethyl-silan
[EINECS(EC#)]

214-191-5
[Molecular Formula]

C6H15BrSi
[MDL Number]

MFCD00000049
[Molecular Weight]

195.17
[MOL File]

1112-48-7.mol
Chemical PropertiesBack Directory
[Melting point ]

-50°C
[Boiling point ]

66 °C24 mm Hg(lit.)
[density ]

1.135 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.456(lit.)
[Fp ]

39°C
[form ]

liquid
[Specific Gravity]

1.14
[Hydrolytic Sensitivity]

8: reacts rapidly with moisture, water, protic solvents
[InChI]

InChI=1S/C6H15BrSi/c1-4-8(7,5-2)6-3/h4-6H2,1-3H3
[InChIKey]

UCKORWKZRPKRQE-UHFFFAOYSA-N
[SMILES]

[Si](Br)(CC)(CC)CC
[CAS DataBase Reference]

1112-48-7(CAS DataBase Reference)
[EPA Substance Registry System]

Silane, bromotriethyl- (1112-48-7)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)
GHS02,GHS05
[Signal word ]

Danger
[Hazard statements ]

H226-H314
[Precautionary statements ]

P280-P305+P351+P338-P310
[Hazard Codes ]

C
[Risk Statements ]

R10:Flammable.
R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 2920 8/PG 2
[WGK Germany ]

3
[F ]

10-21
[TSCA ]

Yes
[HS Code ]

2931.90.9010
Hazard InformationBack Directory
[Uses]

Triethylbromosilane can be used as a protecting group for reactive hydrogens in alcohols, amines, thiols, and carboxylic acids. Organosilanes are hydrogen-like, can be introduced in high yield, and can be removed under selective conditions.
[Application]

Triethylbromosilane can forms silylated derivatives of alcohols stable to Grignard conditions.
[Reactions]

reacts rapidly with moisture, water, protic solvents
Spectrum DetailBack Directory
[Spectrum Detail]

TRIETHYLBROMOSILANE(1112-48-7)1HNMR
TRIETHYLBROMOSILANE(1112-48-7)IR1
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

1112-48-7(sigmaaldrich)
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