| Identification | More | [Name]
METHYL 4-CHLOROBENZOATE | [CAS]
1126-46-1 | [Synonyms]
4-CHLOROBENZOIC ACID METHYL ESTER
METHYL 4-CHLOROBENZOATE
METHYL P-CHLOROBENZOATE
P-CHLOROBENZOIC ACID METHYL ESTER
RARECHEM AL BF 0077
4-chloro-benzoicacimethylester
Benzoic acid, 4-chloro-, methyl ester
Benzoic acid, p-chloro-, methyl ester
Methyl ester of p-chlorobenzoic acid
4-Chlorobenzoic acid methyl | [EINECS(EC#)]
214-420-9 | [Molecular Formula]
C8H7ClO2 | [MDL Number]
MFCD00000621 | [Molecular Weight]
170.59 | [MOL File]
1126-46-1.mol |
| Chemical Properties | Back Directory | [Appearance]
COLOURLESS TO WHITE CRYSTALS | [Melting point ]
42-44 °C (lit.) | [Boiling point ]
136-137°C 10mm | [density ]
1,382 g/cm3 | [refractive index ]
1.5800 (estimate) | [Fp ]
224 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Solid | [color ]
Off-White | [Merck ]
14,2125 | [BRN ]
1564310 | [InChI]
1S/C8H7ClO2/c1-11-8(10)6-2-4-7(9)5-3-6/h2-5H,1H3 | [InChIKey]
LXNFVVDCCWUUKC-UHFFFAOYSA-N | [SMILES]
COC(=O)c1ccc(Cl)cc1 | [LogP]
2.870 | [CAS DataBase Reference]
1126-46-1(CAS DataBase Reference) | [EPA Substance Registry System]
Benzoic acid, 4-chloro-, methyl ester (1126-46-1) |
| Safety Data | Back Directory | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
IRRITANT | [HS Code ]
29163990 | [Storage Class]
11 - Combustible Solids |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Benzamide, 4-chloro-N-methoxy--->4-chloro-N,N-dimethylbenzamide-->4-Chlorobenzyl alcohol-->1-(4-Chlorophenyl)ethanol-->4-Chlorobenzanilide | [Preparation Products]
1,2,3-Benzothiadiazole-5-carboxylic acid-->4-Chlorobenzoylacetonitrile-->Sodium p-chlorobenzoate-->4-(Butylamino)-benzoic acid, methyl ester-->3-(4-Chlorophenyl)-1H-pyrazol-5-amine-->Methyl 4-vinylbenzoate-->Methyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate-->3-amino-1-(4-chlorophenyl)propan-1-ol-->4-Chloro-N-n-hexylbenzaMide, 97% |
| Hazard Information | Back Directory | [Chemical Properties]
COLOURLESS TO WHITE CRYSTALS | [Uses]
Methyl 4-chlorobenzoate was used in quantitative determination of chlorophenoxyisobutyrate (CPIB) and salicylic acid, the metabolites of clofibrate and aspirin, by GC-MS method. | [Synthesis Reference(s)]
Synthesis, p. 790, 1981 DOI: 10.1055/s-1981-29595 | [General Description]
Methyl 4-chlorobenzoate undergoes room temperature Pd-mediated hydrodehalogenation with KF and polymethylhydrosiloxane (PMHS) to yield methyl benzoate. It undergoes Suzuki-Miyaura coupling reaction with phenylboronic acid in the presence of bis-carbene palladium complex catalyst to yield methyl-(4-phenyl)-benzoate. |
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J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
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https://www.jkchemical.com |
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Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
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Energy Chemical
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400-0056266 |
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www.energy-chemical.com |
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Maya High Purity Chemicals
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