ChemicalBook--->CAS DataBase List--->113136-77-9

113136-77-9

113136-77-9 Structure

113136-77-9 Structure
IdentificationBack Directory
[Name]

CYCLANILIDE
[CAS]

113136-77-9
[Synonyms]

FINISH
Hsdb 7018
Rpa 90946
RPA 090946
CYCLANILIDE
Cyclanilide [iso]
Einecs annex I index 616-110-00-2
1-(2,4-Dichloranilino)-carbonyl-cyclopropan-1-carbonsure
1-(2,4-dichlorophenylcarbamoyl)cyclopropancarboxylic acid
Cyclopropanecarboxamide, 1-carboxy-, N-(2,4-dichlorophenyl)-
1-((2,4-dichlorophenyl)carbaMoyl)cyclopropanecarboxylic acid
1-(2,4-dichloroanilinocar bonyl) cyclopropane carboxylic acid
1-[[(2,4-Dichlorophenyl)amino]carbonyl]cyclopropane carboxylic acid
1-[(2,4-Dichlorophenyl)aminocarbonyl]-1-cyclopropanecarboxylic acid
Cyclopropanecarboxylic acid, 1-(((2,4-dichlorophenyl)amino)carbonyl)-
cyclanilide 1-(2,4-dichloroanilinocarbonyl)cyclopropanecarboxylic acid
[EINECS(EC#)]

419-150-7
[Molecular Formula]

C11H9Cl2NO3
[MDL Number]

MFCD03792791
[MOL File]

113136-77-9.mol
[Molecular Weight]

274.1
Chemical PropertiesBack Directory
[Appearance]

A white or pale yellow, crystalline or powdery solid. No characteristic odor.
[Melting point ]

approximate 196℃
[Boiling point ]

513.2±50.0 °C(Predicted)
[density ]

1.4691-1.4820 g/cm3
[storage temp. ]

0-6°C
[solubility ]

DMSO (Slightly), Methanol (Slightly, Sonicated)
[Water Solubility ]

Practically insoluble in water
[form ]

neat
[pka]

3.39±0.20(Predicted)
[color ]

White to Light yellow
[Henry's Law Constant]

1.4×104 mol/(m3Pa) at 25℃, MacBean (2012)
[InChI]

InChI=1S/C11H9Cl2NO3/c12-6-1-2-8(7(13)5-6)14-9(15)11(3-4-11)10(16)17/h1-2,5H,3-4H2,(H,14,15)(H,16,17)
[InChIKey]

GLWWLNJJJCTFMZ-UHFFFAOYSA-N
[SMILES]

C1(C(NC2=CC=C(Cl)C=C2Cl)=O)(C(O)=O)CC1
[CAS DataBase Reference]

113136-77-9
[EPA Substance Registry System]

Cyclanilide (113136-77-9)
Hazard InformationBack Directory
[Uses]

Cyclanilide is a plant growth regulator that functions by interactting with auxin-regulated processes. Cyclanilide is commonly used on cotton plants to either suppress vegetative growth or accelerate senescence. Cyclanilide is also used as a bioregulator of deciduous fruit trees.
[Potential Exposure]

Cyclanilide, amalonanilate plant growth regulator and fungicide is used as a cotton harvest aid
[First aid]

Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respira- tion with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin or eyes with run- ning water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical obser- vation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inha- lation therapy.
[Shipping]

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.
[Incompatibilities]

May react violently with strong oxidi- zers, bromine, 90% hydrogen peroxide, phosphorus trichloride, silver powders, or dust. Incompatible with silver compounds. Mixture with some silver compounds forms explosive salts of silver oxalate. Keep away from reducing agents, oxidizers, sulfuric acid, caustics, ammonia, aliphatic amines, alkanolamines, isocyanates, alkylene oxides, epi- chlorohydrin. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water, and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocya- nates, mercaptans, nitrides, sulfides (releasing heat, toxic, and possibly flammable gases), thiosulfates, and dithionites (releasing hydrogen sulfate and oxides of sulfur).
[Description]

Cyclanilide is a plant growth regulator. It has a modrate aqueous solubility and is relatively volatile. It is not persistent in soil systems but may be in water under some conditions. Cyclanilide has a low mammalian toxicity but may cause adverse reproduction/development effects and is a possible neurotoxin. It is moderately toxic to most fauna and flora.
[Chemical Properties]

A white or pale yellow, crystalline or powdery solid. No characteristic odor.
[Waste Disposal]

Dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. In accordance with 40CFR165 recommendations for the disposal of pesti- cides and pesticide containers. noncombustible containers should be crushed and buried under more than 40 cm of soil . Must be disposed properly by following package label directions or by contacting your local or federal envi- ronmental control agency, or by contacting your regional EPA office.
[Definition]

ChEBI:Cyclanilide is a monocarboxylic acid that is cyclopropanecarboxylic acid that is substituted by a 3,5-dichlorophenylcarbamoyl group at position 1. It is a plant growth regulator which is used as a cotton harvest aid. It has a role as a plant growth regulator and a fungicide. It is a dichlorobenzene, a member of cyclopropanes, an anilide and a monocarboxylic acid.
[Production Methods]

Cyclanilide is commercially produced through a specialised chemical synthesis involving substituted anilides. While detailed public documentation on its exact industrial synthesis is limited, the process typically starts with the preparation of a substituted aniline derivative, which is then reacted with appropriate acylating agents to form the cyclanilide structure.
[Mechanism of action]

Inhibits the transport of auxin particularly in meristematic plant tissue
[Pesticide Type]

Plant Growth Regulator
Safety DataBack Directory
[Symbol(GHS) ]

Skull and Crossbones (GHS06)Environment (GHS09)
GHS06,GHS09
[Signal word ]

Danger
[Hazard statements ]

H301-H332-H411
[Precautionary statements ]

P261-P264-P270-P273-P301+P310-P304+P340+P312
[Hazard Codes ]

Xn,N
[Risk Statements ]

22-51/53
[Safety Statements ]

61
[RIDADR ]

2811
[WGK Germany ]

2
[HS Code ]

2924.29.4700
[REACH Registrations]

Inactive
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[Hazardous Substances Data]

113136-77-9(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Tetrabutylammonium bromide-->1-Cyclopropyl-6,7-difluoro-1,4-dihydro-8-methoxy-4-oxo-3-quinolinecarboxylic acid ethyl ester-->AROMA-->2,4-Dichloroaniline
Spectrum DetailBack Directory
[Spectrum Detail]

CYCLANILIDE(113136-77-9)1HNMR
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