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115262-01-6

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115262-01-6 Structure

115262-01-6 Structure
IdentificationBack Directory
[Name]

TriMethyl(broModifluoroMethyl)silane
[CAS]

115262-01-6
[Synonyms]

(Bromodifluoromethyl)
Difluorobromomethylsilane
TriMethyl(broModifluoroMethyl)silane
(BroModifluoroMethyl)triMethylsilane
Bromodifluoro(trimethylsilyl)methane
Silane, (bromodifluoromethyl)trimethyl-
(Bromodifluoromethyl)trimethylsilane 98%
Trimethyl(bromodifluoromethyl)silane 97%
(Bromodifluoromethyl)trimethylsilane >
TriMethyl(broModifluoroMethyl)silane ISO 9001：2015 REACH
[EINECS(EC#)]

806-938-4
[Molecular Formula]

C4H9BrF2Si
[MDL Number]

MFCD18641931
[MOL File]

115262-01-6.mol
[Molecular Weight]

203.101
Chemical PropertiesBack Directory
[Boiling point ]

108°C(lit.)
[density ]

1.306
[refractive index ]

n/D1.407
[Fp ]

46℃
[storage temp. ]

-20°C
[form ]

liquid
[color ]

clear
[InChIKey]

WDZVWBWAUSUTTO-UHFFFAOYSA-N
[CAS DataBase Reference]

115262-01-6
Safety DataBack Directory
[Risk Statements ]

11
[Safety Statements ]

24/25
[RIDADR ]

UN 1993C 3 / PGIII
[TSCA ]

No
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29319090
Hazard InformationBack Directory
[Uses]

Novel difluorocarbene source for the efficient difluoromethylenation of alkenes/alkynes and difluoromethylation of O-, S-, and N-nucleophiles.
[Reactions]

(1) Difluoromethylenation of TMSCN.
TriMethyl(broModifluoroMethyl)silane
Ref. J. Org. Chem. 2012, 77, 5850?5855.
(2) Difluoromethylenation of benzyl and alkylzinc halides.
TriMethyl(broModifluoroMethyl)silane
Ref. Org. Lett. 2013, 15, 917 – 919.
(3) Fluorination aminocarbonylation of aldehydes
TriMethyl(broModifluoroMethyl)silane
Ref. Angew. Chem. Int. Ed. 2022, e202115467
[General Description]

(Bromodifluoromethyl)trimethylsilane (TMSCF2Br) is commonly used as a source to generate dilfluorocarbene. TMSCF3 (Ruppert–Prakash reagent) and BBr3 undergoes fast halogen–exchange reaction to form MSCF2Br.
[References]

[1]Angewandte Chemie International Edition.DOI :10.1002/anie.202283811
[2]The Journal of Organic Chemistry.DOI :10.1021/acs.orglett.2c02899
Spectrum DetailBack Directory
[Spectrum Detail]

TriMethyl(broModifluoroMethyl)silane(115262-01-6)1HNMR
TriMethyl(broModifluoroMethyl)silane(115262-01-6)FT-IR
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