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119-27-7

119-27-7 Structure

119-27-7 Structure
IdentificationMore
[Name]

1-Methoxy-2,4-dinitrobenzene
[CAS]

119-27-7
[Synonyms]

2,4-DINITROANISOLE
2,4-DINITROMETHOXYBENZENE
1-methoxy-2,4-dinitro-benzen
1-Methoxy-2,4-dinitrobenzene
1-methoxy-2,4-dinitro-Benzene
2,4-Dinitro-1-methoxy-benzene
2,4-Dinitroanisol
2,4-dinitro-anisol
2,4-Dinitrophenyl methyl ether
2,4-dinitrophenylmethylether
2,4-Nitroanisole
alpha-Dinitroanisole
Anisole, 2,4-dinitro-
Dinitroanisole
-Dinitroanisole
2,4-Dinitroanisole99%
2,4-dimitroanisole
3,4-Dinitromethoxybenzene
1,3-Dinitro-4-methoxybenzene
[EINECS(EC#)]

204-310-9
[Molecular Formula]

C7H6N2O5
[MDL Number]

MFCD00035745
[Molecular Weight]

198.13
[MOL File]

119-27-7.mol
Chemical PropertiesBack Directory
[Appearance]

yellow crystals or crystalline powder
[Melting point ]

94-96 °C(lit.)
[Boiling point ]

207°C/12mm
[density ]

1.34 g/mL at 25 °C(lit.)
[vapor pressure ]

0.001Pa at 25℃
[refractive index ]

1.5460 (estimate)
[Fp ]

207°C/12mm
[Water Solubility ]

Solubility in hot methanol; almost transparency. Water solubility, 155 mg/L 15°C. Completely soluble in ethyl acetate & acetone.
[BRN ]

1881474
[LogP]

1.58 at 25℃
[CAS DataBase Reference]

119-27-7(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzene, 1-methoxy-2,4-dinitro-(119-27-7)
[EPA Substance Registry System]

119-27-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R40:Limited evidence of a carcinogenic effect.
R22:Harmful if swallowed.
[Safety Statements ]

S7/8:Keep container tightly closed and dry .
S22:Do not breathe dust .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[WGK Germany ]

3
[RTECS ]

DA5250000
[TSCA ]

Yes
[HazardClass ]

6.1
[Safety Profile]

Poison by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS of AROMATIC HYDROCARBONS and NITRATES.
[Toxicity]

rat,LDLo,oral,100mg/kg (100mg/kg),National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. Vol. 5, Pg. 16, 1953.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Methanol-->2,4-Dinitrochlorobenzene-->Basic Orange 2-->Phenolohthalein paper-->2H-1,2,3-Triazole,2-(2,4-dinitrophenyl)-4-nitro--->2,4-Dinitrophenol-->2H-1,2,3-Triazole,4-nitro-(9CI)-->Potassium methoxide-->Sodium Methoxide-->Dimethyl carbonate-->4-Methoxyphenylboronic acid-->Anisole
[Preparation Products]

Fast Scarlet RC Base-->2-Amino-4-nitro anisidine-->4-Acetylamino-2-(diallylamino)anisole-->Mepiquat-->2-Nitroanisole-->4-Nitroanisole-->2-Amino-4-nitro anisidine
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1-Methoxy-2,4-dinitrobenzene(119-27-7).msds
Hazard InformationBack Directory
[Chemical Properties]

yellow crystals or crystalline powder
[Uses]

It can be used as a dye ingredient. It is one of the insensitive nitroaromatic ingredients increasingly used as a replacement for 2,4,6-trinitrotoluene (TNT) in munitions.
[Definition]

ChEBI: A member of the class of dinitroanisoles that is 2-nitroanisole in which the hydrogen para to the methoxy group is replaced by a second nitro group.
[Production Methods]

2,4-Dinitrochlorobenzene is treated with methanolic sodium hydroxide in a process similar to that described for 4-nitroanisole. 2,4-Dinitrophenetole [610-54-8] is similarly manufactured by using ethanol.
[Flammability and Explosibility]

Notclassified
[Purification Methods]

Purify the anisole by repeated crystallisation from EtOH, MeOH or H2O and dry it in a vacuum desiccator over P2O5. The naphthalene complex has m 69o (from EtOH). [Beilstein 6 III 869, 6 IV 1385.
Spectrum DetailBack Directory
[Spectrum Detail]

1-Methoxy-2,4-dinitrobenzene(119-27-7)MS
1-Methoxy-2,4-dinitrobenzene(119-27-7)1HNMR
1-Methoxy-2,4-dinitrobenzene(119-27-7)13CNMR
1-Methoxy-2,4-dinitrobenzene(119-27-7)IR1
1-Methoxy-2,4-dinitrobenzene(119-27-7)IR2
1-Methoxy-2,4-dinitrobenzene(119-27-7)IR3
Tags:119-27-7 Related Product Information
83-66-9 655-07-2 119-27-7 16536-30-4