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1190-92-7

1190-92-7 Structure

1190-92-7 Structure
IdentificationMore
[Name]

1-DIMETHYLAMINO-2-NITROETHYLENE
[CAS]

1190-92-7
[Synonyms]

1-DIMETHYLAMINO-2-NITROETHYLENE
N1,N1-Dimethyl-2-nitroeth-1-en-1-amine
N,N-DIMETHYL-2-NITRO-1-ETHYLENAMINE
N,N-DIMETHYL-N-(2-NITROVINYL)AMINE
SPECS AN-308/25123016
(E)-N,N-Dimethyl-2-nitroethenamine
1-(Dimethylamino)-2-nitroethene
n,n-dimethyl-2-nitroethyleneamine
1-(Dimethylamino)-2-nitroethylene 98%
[EINECS(EC#)]

628-409-5
[Molecular Formula]

C4H8N2O2
[MDL Number]

MFCD00051519
[Molecular Weight]

116.12
[MOL File]

1190-92-7.mol
Chemical PropertiesBack Directory
[Melting point ]

103-107 °C(lit.)
[Boiling point ]

161℃
[density ]

1.073
[Fp ]

51℃
[storage temp. ]

Keep Cold
[solubility ]

sol alcohols, ethers, chloroform, acetone; slightly sol n-hexane
[form ]

crystalline solid
[pka]

2.71±0.70(Predicted)
[color ]

Orange
[BRN ]

1903136
[InChI]

InChI=1S/C4H8N2O2/c1-5(2)3-4-6(7)8/h3-4H,1-2H3
[InChIKey]

JKOVQYWMFZTKMX-ONEGZZNKSA-N
[SMILES]

C(N(C)C)=C[N+]([O-])=O
[CAS DataBase Reference]

1190-92-7(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
[Signal word ]

Danger
[Hazard statements ]

H319-H302-H315-H317-H318-H335
[Precautionary statements ]

P261-P280-P305+P351+P338-P280a-P304+P340-P405-P501a
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
R43:May cause sensitization by skin contact.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

IRRITANT, KEEP COLD
[HS Code ]

29211990
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Dam. 1
Skin Irrit. 2
Skin Sens. 1
STOT SE 3
Hazard InformationBack Directory
[Uses]

1-(Dimethylamino)-2-nitroethylene undergoes addition-elimination reaction with indoles to form the corresponding 3-(2-nitrovinyl)indoles.
[Uses]

1-Dimethylamino-2-nitroethylene is widely used in organic reactions.
[Preparation]

1-Dimethylamino-2-nitroethylene can be prepared by reaction of N,N-Dimethylformamide Diethyl Acetal (85% yield) or N,N-Dimethylformamide-Dimethyl Sulfate complex (60%) with Nitromethane; condensation of Triethyl Orthoformate with MeNO2 in the presence of DMF (52%), or addition-elimination reaction of 1-Nitro-2-phenylthioethylene with Me2NH (74%).
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

N1,N1-Dimethyl-2-nitroeth-1-en-1-amine, 97%(1190-92-7)
[Alfa Aesar]

1-Dimethylamino-2-nitroethylene, 98%(1190-92-7)
[Sigma Aldrich]

1190-92-7(sigmaaldrich)
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1190-92-7