ChemicalBook--->CAS DataBase List--->12045-63-5

12045-63-5

12045-63-5 Structure

12045-63-5 Structure
IdentificationMore
[Name]

TITANIUM BORIDE
[CAS]

12045-63-5
[Synonyms]

TIB2 F
TIB2 SE
TITANIUM BORIDE
TITANIUM DIBORIDE
titaniumboride(tib2)
TITANIUM BORIDE, POWDER, CA. 10 MICRON
Titaniumboride,99%
TIB2 SE TITANIUM DIBORIDE GRADE SE-A PRODUCT OF H.C. STARCK
TITANIUM DIBORIDE GRADE D-A PRODUCT OF H.C. STARCK
TITANIUM DIBORIDE GRADE E-A PRODUCT OF H.C. STARCK
TITANIUM BORIDE , 2-6 MICRON
Titanium boride, 99.5% (metals basis)
Titanium(II) boride
[EINECS(EC#)]

234-961-4
[Molecular Formula]

B2Ti
[MDL Number]

MFCD00049595
[Molecular Weight]

69.49
[MOL File]

12045-63-5.mol
Chemical PropertiesBack Directory
[Appearance]

GREY POWDER
[Melting point ]

2900-3225°C
[density ]

4.52 g/mL at 25 °C(lit.)
[solubility ]

Soluble in hydrogen peroxide and sulfuric acid.
[form ]

powder
[color ]

gray refractory solid; hexagonal, hexane
[Specific Gravity]

4.52
[Resistivity]

16–28.4 (ρ/μΩ.cm)
[Water Solubility ]

Insoluble in water.
[Crystal Structure]

Hexagonal
[InChIKey]

QYEXBYZXHDUPRC-UHFFFAOYSA-N
[Uses]

Metallurgical additive, high-temperature electrical conductor, refractory, cermet component, coatings resistant to attack by molten metals, aluminum manufacture, super alloys.
[CAS DataBase Reference]

12045-63-5(CAS DataBase Reference)
[EPA Substance Registry System]

Titanium boride (TiB2) (12045-63-5)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S36:Wear suitable protective clothing .
[WGK Germany ]

3
[TSCA ]

Yes
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Boron carbide-->Titanium tetrachloride-->Boron trichloride-->Hydrogen-->TITANIUM DIOXIDE
Hazard InformationBack Directory
[Chemical Properties]

GREY POWDER
[Physical properties]

Gray crystals, superconducting at 1.26 K. High-temperature electrical conductor, used as crucible material for handling molten metals such as Al, Zn, Cd, Bi, Sn, and Rb; strongly corroded by liquid metals such as Ti, Zr, V, Nb, Ta, Cr, Mn, Fe, Co, Ni, and Cu. Begins to be oxidized in air above 1100–1400°C. Corrosion resistance in hot concentrated brines. Maximum operating temperature 1000°C (reducing) and 800°C (oxidizing).
[Application]

Titanium diboride is a conductive composite material. Making conductive boron nitride (evaporation boat) with Titanium boride (TiB2) and boron nitride (BN) is the main component of vacuum aluminum plating equipment. It can also be used as an important component of multi-component composite materials. Titanium boride can be combined with TiC, TiN, SiC and other materials to form composite materials for cutting tools. It can also be used as a component to make armor protection materials. The best material for components and functional devices. TiB2 is used to metallurgical additive, high-temperature electrical conductor, refractory, cermet component, coatings resistant to attack by molten metals, aluminum manufacture, super alloys.Used as a cathode material in aluminum smelting and can be shaped by electrical discharge machining. Specialized applications in such areas as impact resistant armor, cutting tools, crucibles, neutron absorbers and wear resistant coatings.
[Preparation]

Synthesis of titanium diboride through reduction of titanium dioxide by boron carbide and carbon, and its reaction equation
2TiO2+B4C+3C=2TiB2+4CO
Vapor Deposition
Using TiCl4 and BCl3 as raw materials, with the participation of H2, the deposition temperature is 800 ~ 1000 ℃, abrasive-grade and electronic-grade products can be obtained. The reaction equation
TiCl4+2BCl3+5H2=TiB2+10HCl
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Titanium boride, 99.5% (metals basis)(12045-63-5)
[Sigma Aldrich]

12045-63-5(sigmaaldrich)
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