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12154-95-9

12154-95-9 Structure

12154-95-9 Structure
IdentificationBack Directory
[Name]

CYCLOPENTADIENYLIRON DICARBONYL DIMER, 99
[CAS]

12154-95-9
[Synonyms]

Bis(cyclopentadienyl)dicarbonyliron
Cyclopentadienyldicarbonyliron dimer
Bis(pi-cyclopentadienylirondicarbonyl)
Bis-(cyclopentadienyl)-iron dicarbonyl
Dicyclopentadienyliron dicarbonyl dimer
Bis(pi-cyclopentadienyldicarbonyl iron)
Dicarbonyl-pi-cyclopentadienyliron dimer
Tetracarbonylbis(cyclopentadienyl)diiron
dicyclopentadienyl-di-iron tetracarbonyl
Bis(dicarbonylcyclopentadienyliron), 99%.
CYCLOPENTADIENYLIRON DICARBONYL DIMER, 99
Diiron, bis(cyclopentadienyl)tetracarbonyl-
Di-pi-cyclopentadienyl-tetracarbonyl-di-iron
Iron, dicarbonyl-pi-cyclopentadienyl-, dimer
Cyclopentadienyliron dicarbonyl diMer, 99% 25GR
Iron, dicarbonyl-(eta-5-cyclopentadienyl)-, dimer
benzoyldicarbonyl(n5-2,4-cyclopentadien-1-yl)-Iron
Iron,benzoyldicarbonyl(n5-2,4-cyclopentadien-1-yl)-
Di-mu-Carbonyldicarbonyldi-pi-cyclopentadienyldiiron
di-mu-carbonyldicarbonylbis(eta5-cyclopenta-2,4-dien-1-yl)diiron
Iron, di-mu-carbonyldicarbonyldi-pi-cyclopentadienyldi-, (Fe-Fe)
Iron, di-mu-carbonyldicarbonylbis(eta(5)-2,4-cyclopentadien-1-yl)di-,
[EINECS(EC#)]

235-276-3
[Molecular Formula]

C12H14FeO2
[MDL Number]

MFCD00135625
[MOL File]

12154-95-9.mol
[Molecular Weight]

246.083
Chemical PropertiesBack Directory
[Appearance]

RED-PURPLE TO VERY DARK BROWN CRYSTALLINE POWDER
[Melting point ]

194°C (dec.)
[solubility ]

very sol CHCl3, pyridine, and alcohol; sol CCl4 and CS2; slightly sol pentane; insol H2O.
[form ]

crystal
[color ]

red to purple
[Water Solubility ]

It is readily soluble in moderate polar organic solvents such as chloroform and pyridine, but less soluble in carbon tetrachloride and carbon disulfide. It is sparingly soluble in water.
[Sensitive ]

Air & Moisture Sensitive
[Exposure limits]

ACGIH: TWA 1 mg/m3
NIOSH: TWA 1 mg/m3
[InChI]

1S/2C5H5.4CO.2Fe/c2*1-2-4-5-3-1;4*1-2;;/h2*1-5H;;;;;;
[InChIKey]

DHLWUDJVLCWRGH-UHFFFAOYSA-N
[SMILES]

[Fe][Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
Hazard InformationBack Directory
[Chemical Properties]

RED-PURPLE TO VERY DARK BROWN CRYSTALLINE POWDER
[Uses]

Cyclopentadienyliron dicarbonyl dimer is a workhorse in organometallic chemistry because it is inexpensive and rugged. It is also used as a pharmaceutical intermediates and chemical research.
[Application]

Cyclopentadienyliron dicarbonyl dimer, 99 is a binuclear metal carbonyl catalyst used in various carbon-carbon bond forming reactions; a free radical initiator; a precursor of alkyl and acyl iron complexes useful in organic synthesis.
[General Description]

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.
[reaction suitability]

core: iron
reagent type: catalyst
[storage]

The reagent is stable to air, unaffected by H2O, and can be stored for  long periods of time. Reputed to be very toxic by inhalation and ingestion; avoid breathing of particles or  vapors. Use in a fume hood.
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22-20/22
[Safety Statements ]

22-36/37/39-36/37
[RIDADR ]

UN3466
[WGK Germany ]

3
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

29310099
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Spectrum DetailBack Directory
[Spectrum Detail]

CYCLOPENTADIENYLIRON DICARBONYL DIMER, 99(12154-95-9)Raman
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