| Identification | Back Directory | [Name]
2-(Di-1-adamantylphosphino) dimethylaminobenzene,97% Me-DalPhos | [CAS]
1219080-77-9 | [Synonyms]
Me-Dalphos
97% Me-DalPhos
Di(1-adamantyl)-2-dimethylaminophenylphosphine
2-(Di-1-adaMantylphosphino)diMethylaMinobenzene
2-(Di-1-adamantylphosphino)-N,N-dimethylaniline
Bis(adamant-1-yl)(2-dimethylaminophenyl)phosphine
Di(1-adamantyl)-2-dimethylaminophenylphosphine 98%
2-(Di-1-adamantylphosphino) dimethylaminobenzene,97% Me-DalPhos
2-[Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-N,N-dimethylbenzeneamine | [Molecular Formula]
C28H40NP | [MDL Number]
MFCD17018758 | [MOL File]
1219080-77-9.mol | [Molecular Weight]
421.598 |
| Chemical Properties | Back Directory | [Melting point ]
237-242°C | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
crystal | [pka]
4.67±0.18(Predicted) | [color ]
white to yellow | [Sensitive ]
air sensitive | [InChIKey]
MILNYLCUWRWYBI-XMCXLQRDSA-N | [SMILES]
CN(C)c1ccccc1P([C@@]23C[C@@H]4C[C@@H](C[C@@H](C4)C2)C3)[C@@]56C[C@@H]7C[C@@H](C[C@@H](C7)C5)C6 |
| Questions And Answer | Back Directory | [Reaction]
Versatile ligand for the palladium-catalyzed amination of aryl and heteroaryl chlorides with primary aryl and alkylamines, cyclic and acyclic amines, lithium amide, N-H imines, hydrazones and ammonia.
|
| Hazard Information | Back Directory | [Uses]
2-(Di-1-adamantylphosphino)dimethylaminobenzene is a ligand employed in Pd-?catalyzed cross-?coupling reactions. | [reaction suitability]
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction |
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