| Identification | Back Directory | [Name]
BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER | [CAS]
12246-51-4 | [Synonyms]
Chlorobis(cyclooctene)iridium(I)
Bis(cyclooctene)iridium(I) chloride
Chlorobis(cyclooctene)iridium dimer
Chlorobis(cyclooctene)iridium(Ⅰ) dimer
CHLOROBIS(CYCLOOCTENE)IRIDIUM (I) DIMER
Chlorobis(cyclooctene)iridium(I)dimer,97%
di-μ-chlorotetrakis(cyclooctene)diiridium
Chlorobis(cyclooctene)iridium(I)dimer 97%
DI-MU-CHLOROTETRAKIS(CYCLOOCTENE)DIIRIDIUM
BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER
Chlorobis(cyclooctene)iridium(I) dimer, Ir nominally 42.9%
Di-μ-chloro(tetramethyl)diiridium - (1Z)-cyclooctene (1:4)
Chlorobis(cyclooctene)iridiuM(Ⅰ) diMer, 43% Ir, Product of UMicore | [Molecular Formula]
C32H56Cl2Ir2 8* | [MDL Number]
MFCD00213465 | [MOL File]
12246-51-4.mol | [Molecular Weight]
896.13 |
| Chemical Properties | Back Directory | [Appearance]
Yellow solid | [Melting point ]
160-165 °C (dec.)(lit.)
| [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [solubility ]
Soluble in organic solvents. | [form ]
crystal | [color ]
yellow | [Sensitive ]
moisture sensitive, store cold | [InChI]
InChI=1S/4C8H14.2ClH.2Ir/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;; | [InChIKey]
WBRREXQCZAFSKS-XFCUKONHSA-L | [SMILES]
C1CC[CH][CH]CCC1.C1CC[CH][CH]CCC1.C1CC[CH][CH]CCC1.C1CC[CH][CH]CCC1.Cl[Ir].Cl[Ir] |^1:3,4,11,12,19,20,27,28| |
| Hazard Information | Back Directory | [Chemical Properties]
Yellow solid | [Uses]
Chlorobis(cyclooctene)iridium(I) dime is used as catalyst for Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand, Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions, Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions, Alkylation reactions, Guerbet reaction, Allylic amination reactions in a DNA-diene-iridium(I) hybrid system, Asymmetric hydroamination reactions. | [reaction suitability]
core: iridium
reagent type: catalyst |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-37/39 | [WGK Germany ]
3
| [TSCA ]
No | [HS Code ]
28439000 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
|
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Omkar Lab
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www.omkarlab.com |
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