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12246-51-4

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12246-51-4 Structure

12246-51-4 Structure
IdentificationBack Directory
[Name]

BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER
[CAS]

12246-51-4
[Synonyms]

Chlorobis(cyclooctene)iridium(I)
Bis(cyclooctene)iridium(I) chloride
Chlorobis(cyclooctene)iridium dimer
Chlorobis(cyclooctene)iridium(Ⅰ) dimer
CHLOROBIS(CYCLOOCTENE)IRIDIUM (I) DIMER
Chlorobis(cyclooctene)iridium(I)dimer,97%
di-μ-chlorotetrakis(cyclooctene)diiridium
Chlorobis(cyclooctene)iridium(I)dimer 97%
DI-MU-CHLOROTETRAKIS(CYCLOOCTENE)DIIRIDIUM
BIS(CYCLOOCTENE)IRIDIUM(I) CHLORIDE, DIMER
Chlorobis(cyclooctene)iridium(I) dimer, Ir nominally 42.9%
Di-μ-chloro(tetramethyl)diiridium - (1Z)-cyclooctene (1:4)
Chlorobis(cyclooctene)iridiuM(Ⅰ) diMer, 43% Ir, Product of UMicore
[Molecular Formula]

C32H56Cl2Ir2 8*
[MDL Number]

MFCD00213465
[MOL File]

12246-51-4.mol
[Molecular Weight]

896.13
Chemical PropertiesBack Directory
[Appearance]

Yellow solid
[Melting point ]

160-165 °C (dec.)(lit.)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[solubility ]

Soluble in organic solvents.
[form ]

crystal
[color ]

yellow
[Sensitive ]

moisture sensitive, store cold
[InChI]

InChI=1S/4C8H14.2ClH.2Ir/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;
[InChIKey]

WBRREXQCZAFSKS-XFCUKONHSA-L
[SMILES]

C1CC[CH][CH]CCC1.C1CC[CH][CH]CCC1.C1CC[CH][CH]CCC1.C1CC[CH][CH]CCC1.Cl[Ir].Cl[Ir] |^1:3,4,11,12,19,20,27,28|
Hazard InformationBack Directory
[Chemical Properties]

Yellow solid
[Uses]

Chlorobis(cyclooctene)iridium(I) dime is used as catalyst for Isomerization-hydroboration reactions with nido-carboranyldiphosphine as stabilizing ligand, Hydrogen peroxide oxidation of hydroxamic acids and their subsequent hetero Diels-Alder cycloaddition reactions, Immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions, Alkylation reactions, Guerbet reaction, Allylic amination reactions in a DNA-diene-iridium(I) hybrid system, Asymmetric hydroamination reactions.
[reaction suitability]

core: iridium
reagent type: catalyst
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-37/39
[WGK Germany ]

3
[TSCA ]

No
[HS Code ]

28439000
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
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