| Identification | More | [Name]
Bis(cyclopentadienyl)dimethylzirconium | [CAS]
12636-72-5 | [Synonyms]
BIS(CYCLOPENTADIENYL)DIMETHYLZIRCONIUM
BIS(CYCLOPENTADIENYL)DIMETHYLZIRCONIUM(IV)
BIS(CYCLOPENTADIENYL)ZIRCONIUM DIMETHYL
DIMETHYLZIRCONOCENE
ZIRCONOCENE DIMETHYL
Dimethylcirconocene
Dimethylbis(cyclopentadienyl)zirconium,
Bis(cyclopentadienyl)dimethylzirconium,min.97%
Bis(cyclopentadienyl)dimethylzirconium(IV), 98+%
Bis(cyclopentadienyl)dimethylzirconium, min. 97% | [Molecular Formula]
C12H16Zr | [MDL Number]
MFCD01073786 | [Molecular Weight]
251.48 | [MOL File]
12636-72-5.mol |
| Chemical Properties | Back Directory | [Appearance]
pale yellow to yellow crystals or needles | [Melting point ]
170 °C (dec.)(lit.) | [Boiling point ]
170°C | [storage temp. ]
below 5° C | [form ]
crystal | [color ]
white | [Sensitive ]
Air Sensitive | [InChI]
1S/2C5H5.2CH3.Zr/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H3; | [InChIKey]
BRHODLBZJKAKRN-UHFFFAOYSA-N | [SMILES]
C[Zr]C.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2 | [CAS DataBase Reference]
12636-72-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [TSCA ]
No | [HS Code ]
29310099 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2 |
| Hazard Information | Back Directory | [Chemical Properties]
pale yellow to yellow crystals or needles | [Uses]
Catalyst for:
- Cationic ring-opening polymerization reactions
- Markovnikov-selective intermolecular hydrothiolation of terminal alkynes
- Ziegler-Natta polymerizations of alkenes
- Methylalumination of heterosubstituted arylethynes
- Precatalyst for intramolecular hydroamination/cyclisation of aminoallenes
| [reaction suitability]
core: zirconium
reagent type: catalyst
reaction type: Olefin Metathesis |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
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| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
3A Chemicals
|
| Telephone: |
400-668-9898 |
| Website: |
www.3achem.com |
|