| Identification | More | [Name]
Bis-(1-octyloxy-2,2,6,6-tetramethyl-4-piperidinyl) sebacate | [CAS]
129757-67-1 | [Synonyms]
BIS(1-OCTYLOXY-2,2,6,6-TETRAMETHYL-4-PIPERIDYL) SEBACATE DECANEDIOIC ACID, BIS(2,2,6,6-TETRAMETHYL-4-PIPERIDINYL)ESTER, REACTION PRODUCTS WITH 1,1-DIMETHYLETHYL-HYDROPEROXIDE AND OCTANE TINUVIN 123 decanedioicacid,bis(2,2,6,6-tetramethyl-4-piperidinyl)ester,reactionproduc tswithtert-buhydroperoxideandoctane BIS(1-OCTYLOXY-2,2,6,6-TETRAMETHYL-4-PIP Decanedioic acid, bis(2,2,6,6-tetramethyl-4-piperidinyl) ester, reaction products with tert-Bu hydroperoxide and octane Sebazinsure, bis(2,2,6,6-tetramethyl-piperidinyl)-ester, Reaktionsprodukt mit 1,1-Dimethylethylhydroperoxid und Oktan BIS-(1-OCTYLOXY-2,2,6,6-TETRAMETHYL-4-PIPERIDINYL) SEBACATE Bis(2,2,6,6-tetramethyl-4-piperidinyl decanedioate reaction products with 1,1-dimethyl ethyl hydroperoxide and octane HALS HS-112 Light Stabilizer-123 Decanedioic acid bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidinyl) ester Decanedioic acid bis[2,2,6,6-tetramethyl-1-(octyloxy)-4-piperidinyl] ester Sebacic acid bis(1-octyloxy-2,2,6,6-tetramethylpiperidine-4-yl) ester Sebacic acid bis[1-(octyloxy)-2,2,6,6-tetramethylpiperidin-4-yl] ester | [EINECS(EC#)]
406-750-9 | [Molecular Formula]
C44H84N2O6 | [MDL Number]
MFCD02094713 | [Molecular Weight]
737.15 | [MOL File]
129757-67-1.mol |
| Questions And Answer | Back Directory | [Preparation]
In a 500mL three-necked flask equipped with a condenser, a constant-pressure dropping funnel, a water separator, and a mechanical stirrer, di(2,2,6,6-tetramethyl-tetrahydroxypiperidine) sebacate aminooxy radical (A), n-octane (C), and catalyst (D) were added. After stirring and heating to dissolve, 70% tert-butyl hydrogen peroxide (B) was added dropwise to the reaction flask. After the addition was complete, the reaction was maintained at the desired temperature. After the reaction was completed, the reaction solution was cooled to room temperature, and the catalyst was filtered off. Under stirring conditions, an appropriate amount of sodium sulfite aqueous solution was added dropwise to the mother liquor to decompose excess tert-butyl hydrogen peroxide. Stirring was stopped when the solution did not change color when tested with starch-potassium iodide test paper. The aqueous layer was separated, and the organic layer was washed twice with hot water and decolorized with activated carbon. The washed and decolorized organic phase was distilled under reduced pressure using a rotary evaporator to remove n-octane, yielding a pale yellow oily product, which is the target product, Bis-(1-octyloxy-2,2,6,6-tetramethyl-4-piperidinyl) sebacate. |
| Chemical Properties | Back Directory | [density ]
1.028 g/mL at 25 °C(lit.)
| [vapor pressure ]
0-0Pa at 20-25℃ | [refractive index ]
n20/D 1.479(lit.)
| [Fp ]
>230 °F
| [solubility ]
H2O: <6 ppm at 20 °C
| [Water Solubility ]
6mg/L at 20℃ | [InChIKey]
OSIVCXJNIBEGCL-UHFFFAOYSA-N | [SMILES]
C(C)(C)(C)OO.C(CCC)CCCC.O(C1CC(C)(C)NC(C)(C)C1)C(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 | [LogP]
16.8 at 20℃ | [CAS DataBase Reference]
129757-67-1(CAS DataBase Reference) | [EPA Substance Registry System]
129757-67-1(EPA Substance) |
| Safety Data | Back Directory | [Hazard statements ]
H413 | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) . S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
1
| [TSCA ]
TSCA listed | [REACH Registrations]
Active | [Storage Class]
10 - Combustible liquids |
| Hazard Information | Back Directory | [Chemical Properties]
Liquid | [Uses]
Easily emulsified in water-borne systems. Miscible to >50% with xylene, MEK, and other paint solvents. | [General Description]
Bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl) sebacate is a hindered amine light stabilizer (HALS) that is effective in retarding degradation through thermal and photo-oxidation process. It can be used in wood and plastic based coatings. |
|
| Company Name: |
T&W GROUP
|
| Telephone: |
021-61551611 13296011611 |
| Website: |
www.trustwe.com/ |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
|