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129757-67-1

129757-67-1 Structure

129757-67-1 Structure
IdentificationMore
[Name]

Bis-(1-octyloxy-2,2,6,6-tetramethyl-4-piperidinyl) sebacate
[CAS]

129757-67-1
[Synonyms]

BIS(1-OCTYLOXY-2,2,6,6-TETRAMETHYL-4-PIPERIDYL) SEBACATE
DECANEDIOIC ACID, BIS(2,2,6,6-TETRAMETHYL-4-PIPERIDINYL)ESTER, REACTION PRODUCTS WITH 1,1-DIMETHYLETHYL-HYDROPEROXIDE AND OCTANE
TINUVIN 123
decanedioicacid,bis(2,2,6,6-tetramethyl-4-piperidinyl)ester,reactionproduc
tswithtert-buhydroperoxideandoctane
BIS(1-OCTYLOXY-2,2,6,6-TETRAMETHYL-4-PIP
Decanedioic acid, bis(2,2,6,6-tetramethyl-4-piperidinyl) ester, reaction products with tert-Bu hydroperoxide and octane
Sebazinsure, bis(2,2,6,6-tetramethyl-piperidinyl)-ester, Reaktionsprodukt mit 1,1-Dimethylethylhydroperoxid und Oktan
BIS-(1-OCTYLOXY-2,2,6,6-TETRAMETHYL-4-PIPERIDINYL) SEBACATE
Bis(2,2,6,6-tetramethyl-4-piperidinyl decanedioate reaction products with 1,1-dimethyl ethyl hydroperoxide and octane
HALS HS-112
Light Stabilizer-123
Decanedioic acid bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidinyl) ester
Decanedioic acid bis[2,2,6,6-tetramethyl-1-(octyloxy)-4-piperidinyl] ester
Sebacic acid bis(1-octyloxy-2,2,6,6-tetramethylpiperidine-4-yl) ester
Sebacic acid bis[1-(octyloxy)-2,2,6,6-tetramethylpiperidin-4-yl] ester
[EINECS(EC#)]

406-750-9
[Molecular Formula]

C44H84N2O6
[MDL Number]

MFCD02094713
[Molecular Weight]

737.15
[MOL File]

129757-67-1.mol
Questions And AnswerBack Directory
[Preparation]

In a 500mL three-necked flask equipped with a condenser, a constant-pressure dropping funnel, a water separator, and a mechanical stirrer, di(2,2,6,6-tetramethyl-tetrahydroxypiperidine) sebacate aminooxy radical (A), n-octane (C), and catalyst (D) were added. After stirring and heating to dissolve, 70% tert-butyl hydrogen peroxide (B) was added dropwise to the reaction flask. After the addition was complete, the reaction was maintained at the desired temperature. After the reaction was completed, the reaction solution was cooled to room temperature, and the catalyst was filtered off. Under stirring conditions, an appropriate amount of sodium sulfite aqueous solution was added dropwise to the mother liquor to decompose excess tert-butyl hydrogen peroxide. Stirring was stopped when the solution did not change color when tested with starch-potassium iodide test paper. The aqueous layer was separated, and the organic layer was washed twice with hot water and decolorized with activated carbon. The washed and decolorized organic phase was distilled under reduced pressure using a rotary evaporator to remove n-octane, yielding a pale yellow oily product, which is the target product, Bis-(1-octyloxy-2,2,6,6-tetramethyl-4-piperidinyl) sebacate.
Chemical PropertiesBack Directory
[density ]

1.028 g/mL at 25 °C(lit.)
[vapor pressure ]

0-0Pa at 20-25℃
[refractive index ]

n20/D 1.479(lit.)
[Fp ]

>230 °F
[solubility ]

H2O: <6 ppm at 20 °C
[Water Solubility ]

6mg/L at 20℃
[InChIKey]

OSIVCXJNIBEGCL-UHFFFAOYSA-N
[SMILES]

C(C)(C)(C)OO.C(CCC)CCCC.O(C1CC(C)(C)NC(C)(C)C1)C(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1
[LogP]

16.8 at 20℃
[CAS DataBase Reference]

129757-67-1(CAS DataBase Reference)
[EPA Substance Registry System]

129757-67-1(EPA Substance)
Safety DataBack Directory
[Hazard statements ]

H413
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

1
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[Storage Class]

10 - Combustible liquids
Hazard InformationBack Directory
[Chemical Properties]

Liquid
[Uses]

Easily emulsified in water-borne systems. Miscible to >50% with xylene, MEK, and other paint solvents.
[General Description]

Bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl) sebacate is a hindered amine light stabilizer (HALS) that is effective in retarding degradation through thermal and photo-oxidation process. It can be used in wood and plastic based coatings.
Spectrum DetailBack Directory
[Spectrum Detail]

Bis-(1-octyloxy-2,2,6,6-tetramethyl-4-piperidinyl) sebacate(129757-67-1)IR
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