ChemicalBook--->CAS DataBase List--->13048-33-4

13048-33-4

13048-33-4 Structure

13048-33-4 Structure
IdentificationMore
[Name]

Hexamethylene diacrylate
[CAS]

13048-33-4
[Synonyms]

1,6-BIS(ACRYLOYLOXY)HEXANE
1,6-HEXAMETHYLENE DIACRYLATE
1,6-HEXANEDIOL DIACRYLATE
HDODA
HEXAMETHYLENE GLYCOL DIACRYLATE
1,6-hexanedioldi-2-propenoate
2-Propenoicacid,1,6-hexanediylester
acrylicacid,hexamethyleneester
c716
hexamethyleneacrylate
hexamethylenediacrylate
hexaneglycoldiarcylate
kayaradhdda
nkesterahd
photomer4017
sartomer238
sartomersr238
setaluxuv2243
sr238
viscoat230
[EINECS(EC#)]

235-921-9
[Molecular Formula]

C12H18O4
[MDL Number]

MFCD00008631
[Molecular Weight]

226.27
[MOL File]

13048-33-4.mol
Chemical PropertiesBack Directory
[Melting point ]

6°C
[Boiling point ]

295°C
[density ]

1.01 g/mL at 25 °C(lit.)
[vapor density ]

>1 (vs air)
[vapor pressure ]

<0.01 mm Hg ( 20 °C)
[refractive index ]

n20/D 1.456(lit.)
[Fp ]

>230 °F
[storage temp. ]

Keep in dark place,Inert atmosphere,2-8°C
[solubility ]

Chlroform (Slightly), DMSO (Slightly)
[form ]

Liquid
[color ]

Colourless
[Specific Gravity]

1.01
[Odor]

Mild ester-like odor
[Water Solubility ]

Slightly miscible with water.
[FreezingPoint ]

6
[Sensitive ]

Hygroscopic
[Stability:]

Light Sensitive
[InChI]

1S/C12H18O4/c1-3-11(13)15-9-7-5-6-8-10-16-12(14)4-2/h3-4H,1-2,5-10H2
[InChIKey]

FIHBHSQYSYVZQE-UHFFFAOYSA-N
[SMILES]

C=CC(=O)OCCCCCCOC(=O)C=C
[LogP]

2.81 at 25℃
[CAS DataBase Reference]

13048-33-4(CAS DataBase Reference)
[NIST Chemistry Reference]

Hexamethylene diacrylate(13048-33-4)
[EPA Substance Registry System]

13048-33-4(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H317-H319
[Precautionary statements ]

P261-P264-P272-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/38:Irritating to eyes and skin .
R43:May cause sensitization by skin contact.
[Safety Statements ]

S39:Wear eye/face protection .
[RIDADR ]

UN 3082 9/PG 3
[WGK Germany ]

2
[RTECS ]

AT1430000
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

9
[PackingGroup ]

III
[HS Code ]

29161290
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Aquatic Acute 1
Aquatic Chronic 2
Eye Irrit. 2
Skin Irrit. 2
Skin Sens. 1
[Hazardous Substances Data]

13048-33-4(Hazardous Substances Data)
Hazard InformationBack Directory
[General Description]

Clear yellow liquid.
[Reactivity Profile]

1,6-HEXANEDIOL DIACRYLATE(13048-33-4) is temperature sensitive . May react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen. Can undergo very exothermic addition polymerization reactions. May undergo autoxidation upon exposure to the air to form explosive peroxides.
[Air & Water Reactions]

Insoluble in water.
[Fire Hazard]

This chemical is probably combustible.
[Chemical Properties]

Colorless transparent liquid
[Uses]

1,6-Hexandiol diacrylate is used in organic synthesis; common acrylic monomer in UV -cured inks, adhesives, coatings, photoresists, castings, artificial nails, etc.; monomer in dental composite materials.
[Flammability and Explosibility]

Nonflammable
[Synthesis]

1,6-Hexanediol diacrylate was synthesized by esterification reaction using 1,6-hexanediol and acrylic acid as the raw materials, strongly acidic cationic resin D072 as the catalyst, cyclohexane as the water-carrying agent, and hydroquinone as the polym

Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Hexane-1,6-diyl bisacrylate(13048-33-4).msds
Questions And AnswerBack Directory
[Description]

Hexamethylene diacrylate (also known as hexanediol diacrylate) is a di-functional acrylic monomer that can be polymerized by free radicals. It is used in ultra violet (UV) and electron beam (EB) applications as a reactive component in formulating coatings and inks, furniture and floor coatings, coatings on plastic substrates, varnishes for packing items and more1. The hexamethylene diacrylate cross-linked polystyrene resin can be used for the solid phase synthesis of hydrophobic peptides2-3.
[Sources]

  1. https://www.ashland.com/file_source/Ashland/Documents/Sustainability/rc_hexanediol_diacrylate.pdf
  2. Varkey, J. T., and V. N. Pillai. "Solid phase synthesis of hydrophobic peptides on 1,6-hexanediol diacrylate cross-linked polystyrene resin." Journal of Peptide Science 5.12(1999): 577-81.
  3. https://www.palmerholland.com/Assets/User/Documents/Product/40781/4988/MITM00481.pdf
Spectrum DetailBack Directory
[Spectrum Detail]

Hexamethylene diacrylate(13048-33-4)1HNMR
Hexamethylene diacrylate(13048-33-4)IR1
Hexamethylene diacrylate(13048-33-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

1,6-Hexanediol diacrylate, 99% (reactive esters), stab. with 90ppm hydroquinone(13048-33-4)
[Sigma Aldrich]

13048-33-4(sigmaaldrich)
[TCI AMERICA]

1,6-Bis(acryloyloxy)hexane  (stabilized with MEHQ)(13048-33-4)
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