| Identification | More | [Name]
(S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL | [CAS]
13185-00-7 | [Synonyms]
(+/-)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL
6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL
(+/-)-6,6'-DIBROMO-2,2'-DIHYDROXY-1,1'-BINAPHTHYL
6'-DIBROMO-1,1'-BI-2-NAPHTHOL
AURORA KA-7214
(R)-(-)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL
(R)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL
(R)-(-)-6,6'-DIBROMO-1,1'-BI-NAPHTHOL
(R)-(-)-6,6'-DIBROMO 1,1'-BL-2-NAPHTHOL
(R)-(-)-6,6'-DIBROMO-2,2'-DIHYDROXY-1,1'-BINAPHTHYL
(R)-(-)-6'-DIBROMO-1,1'-BI-2-NAPHTHOL
RACEMIC-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL
(S)-(+)-6,6'-DIBROM-2,2'-DIHYDROXY-1,1'-BINAPHTHYL
(S)-(-)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL
(S)-(+)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL
(S)-6,6'-DIBROMO-1,1'-BI-2-NAPHTHOL
(S)-(+)-6,6'-DIBROMO-1,1'-BI-NAPHTHOL
(S)-6,6'-DIBROMO-1,1'-BINAPHTHYL-2,2'-DIOL
(S)-(+)-6,6'-DIBROMO-2,2'-DIHYDROXY-1,1'-BINAPHTHYL
(S)-(+)-6'-DIBROMO-1,1'-BI-2-NAPHTHOL | [Molecular Formula]
C20H12Br2O2 | [MDL Number]
MFCD00798290 | [Molecular Weight]
444.12 | [MOL File]
13185-00-7.mol |
| Chemical Properties | Back Directory | [Appearance]
white powder | [Melting point ]
195-199 °C(lit.) | [Boiling point ]
546.2±45.0 °C(Predicted) | [density ]
1.761 | [refractive index ]
1.4947 (estimate) | [storage temp. ]
2-8°C | [form ]
Powder | [pka]
7.78±0.50(Predicted) | [color ]
white | [Optical Rotation]
-0.64°(C=1g/100ml CHCL3) | [InChI]
1S/C20H12Br2O2/c21-13-3-5-15-11(9-13)1-7-17(23)19(15)20-16-6-4-14(22)10-12(16)2-8-18(20)24/h1-10,23-24H | [InChIKey]
OORIFUHRGQKYEV-UHFFFAOYSA-N | [SMILES]
Oc1ccc2cc(Br)ccc2c1-c3c(O)ccc4cc(Br)ccc34 | [CAS DataBase Reference]
13185-00-7(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [REACH Registrations]
Active | [HS Code ]
29072900 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
white powder | [Uses]
6,6′-Dibromo-1,1′-bi-2-naphthol is a 1,1′-bi-2-naphthol derivative. Vibrational circular dichroism (VCD), electronic circular dichroism (ECD) and optical rotatory dispersion (ORD) spectra for the enantiomers of 6,6′-dibromo-1,1′-bi-2-naphthol have been evaluated. | [General Description]
6,6′-Dibromo-1,1′-bi-2-naphthol is a 1,1′-bi-2-naphthol derivative. Vibrational circular dichroism (VCD), electronic circular dichroism (ECD) and optical rotatory dispersion (ORD) spectra for the enantiomers of 6,6′-dibromo-1,1′-bi-2-naphthol have been evaluated. |
| Questions And Answer | Back Directory | [Reactions]
1. Ligand (enantiopure version) used to prepare a chiral zirconium catalyst useful in asymmetric Strecker and Mannich-type reactions.
2. Ligand (enantiopure version) used for titanium-catalyzed enantioselective Friedel-Crafts reactions.
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J & K SCIENTIFIC LTD.
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Energy Chemical
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Sigma-Aldrich
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