ChemicalBook--->CAS DataBase List--->131880-16-5

131880-16-5

131880-16-5 Structure

131880-16-5 Structure
IdentificationMore
[Name]

S-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate
[CAS]

131880-16-5
[Synonyms]

5-(TRIFLUOROMETHYL)DIBENZOTHIOPHENIUM TETRAFLUOROBORATE
S-(TRIFLUOROMETHYL)-DIBENZOTHIOPHENIUM TETRAFLUOROBORATE
5-(TRIFLUOROMETHYL)DIBENZOTHIOPHENIUM TE
S-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate 98%
S-(Trifluoromethyl)dibenzothiopheniumtetrafluoroborate98%
[Molecular Formula]

C13H8BF7S
[MDL Number]

MFCD01073545
[Molecular Weight]

340.07
[MOL File]

131880-16-5.mol
Chemical PropertiesBack Directory
[Melting point ]

171-172°C
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[Appearance]

White to light yellow Solid
[InChI]

InChI=1S/C13H8F3S.BF4/c14-13(15,16)17-11-7-3-1-5-9(11)10-6-2-4-8-12(10)17;2-1(3,4)5/h1-8H;/q+1;-1
[InChIKey]

VTVISWLINKWMQZ-UHFFFAOYSA-N
[SMILES]

[B+3]([F-])([F-])([F-])[F-].C([S+]1C2=CC=CC=C2C2C=CC=CC1=2)(F)(F)F
[CAS DataBase Reference]

131880-16-5(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[Hazard Codes ]

Xi
[Safety Statements ]

24/25
[WGK Germany ]

3
[HS Code ]

29349990
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Chemical Properties]

White to yellow solid
[Uses]

5-(Trifluoromethyl)dibenzothiophenium Tetrafluoroborate is used to synthesize ortho-trifluoromethylated and ortho-(fluoro)alkylated pyridine derivatives. It is used as a CF3 source under visible light irradiation for the photoredox-catalyzed trifluoromethylation of electron rich alkene resulting in 1,3-bis(trifluoromethyl)-1-propenyl skeleton.
Spectrum DetailBack Directory
[Spectrum Detail]

S-(Trifluoromethyl)dibenzothiophenium tetrafluoroborate(131880-16-5)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

131880-16-5(sigmaaldrich)
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