ChemicalBook--->CAS DataBase List--->132327-80-1

132327-80-1

132327-80-1 Structure

132327-80-1 Structure
IdentificationMore
[Name]

Nalpha-Fmoc-Ndelta-trityl-L-glutamine
[CAS]

132327-80-1
[Synonyms]

FMOC-GLN(TRT)
FMOC-GLN(TRT)-OH
FMOC-GLUTAMINE(TRT)-OH
FMOC-L-GLN(TRITYL)
FMOC-L-GLN(TRT)
FMOC-L-GLN(TRT)-OH
FMOC-L-GLUTAMINE(TRITYL)
FMOC-L-GLUTAMINE (TRT)
FMOC-N-DELTA-TRITYL-L-GLUTAMINE
FMOC-N-GAMMA-TRITYL-L-GLUTAMINE
FMOC-N-TRITYL-L-GLUTAMINE
NA-FMOC-NG-TRITYL-L-GLUTAMINE
N-ALPHA-9-FLUORENYLMETHOXYCARBONYL-N-GAMMA-TRITYL-GLUTAMINE
N-ALPHA-(9-FLUORENYLMETHOXYCARBONYL)-N-GAMMA-TRITYL-L-GLUTAMINE
N-ALPHA-9-FLUORENYLMETHOXYCARBONYL-N-OMEGA-TRITYL-L-GLUTAMINE
NALPHA-(9-FLUORENYLMETHOXYCARBONYL)-NR-TRITYL-GLUTAMINE
N-ALPHA-(9-FLUORENYLMETHYLOXYCARBONYL)-N-GAMMA-TRITYL-L-GLUTAMINE
N-ALPHA-FMOC-N-DELTA-TRITYL-L-GLUTAMINE
N-ALPHA-FMOC-N-GAMMA-TRITYL-L-GLUTAMINE
N-ALPHA-FMOC-N-TRITYL-L-GLUTAMINE
[EINECS(EC#)]

603-564-1
[Molecular Formula]

C39H34N2O5
[MDL Number]

MFCD00077056
[Molecular Weight]

610.7
[MOL File]

132327-80-1.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

165-172 °C
[Boiling point ]

873.5±65.0 °C(Predicted)
[density ]

1.256±0.06 g/cm3(Predicted)
[storage temp. ]

2-8°C
[solubility ]

Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
[form ]

Powder
[pka]

3.73±0.10(Predicted)
[color ]

White to yellow
[Optical Rotation]

[α]/D -14.0±1.5°, c = 1% in DMF
[Sensitive ]

Moisture Sensitive
[Detection Methods]

T,NMR,Rotation
[BRN ]

4343953
[Major Application]

peptide synthesis
[InChIKey]

WDGICUODAOGOMO-DHUJRADRSA-N
[SMILES]

C(O)(=O)[C@H](CCC(N)=O)N(C(OCC1C2=C(C=CC=C2)C2=C1C=CC=C2)=O)C(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
[CAS DataBase Reference]

132327-80-1(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H317-H413
[Precautionary statements ]

P261-P280g-P302+P352a-P321-P333+P313-P501a
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[F ]

10-21
[HS Code ]

29242990
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powde
[Uses]

Fmoc-Gln(trt)-OH, is an amino acid derivative used in chemical synthesis and peptide chemistry.
[General Description]

Fmoc-Gln(Trt)-OH has good solubility properties in most organic solvents, and its use has been shown to result in significantly purer peptides than other derivatives used for the introduction of Gln [1]. Coupling can be performed by standard procedures. The trityl-protecting group is normally removed by 95% TFA in 1-3 hours, with no alkylation of Trp.

The product number for this product was previously 04-12-1090.

To obtain a certificate of analysis (CoA) of a lot that begins with the letter “A”, please select the option in the right hand menu “Request a COA for Lot#s starting with A”.
[reaction suitability]

reaction type: Fmoc solid-phase peptide synthesis
[Synthesis]

At room temperature, 9- BBN-protected glutamine ( 1 mmol) was stirred vigorously in acetonitrile ( 2 mL), then disodium hydrogen phosphate ( 3 mmol , 426 mg) was added to the resulting reaction solution, and trifluoroperoxyacetic acid ( 6 mL , 0.5 M in CH
Spectrum DetailBack Directory
[Spectrum Detail]

Nalpha-Fmoc-Ndelta-trityl-L-glutamine(132327-80-1)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

132327-80-1(sigmaaldrich)
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