| Identification | Back Directory | [Name]
N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (R,R)-Ts-DENEB 1333981-84-2 | [CAS]
1333981-84-2 | [Synonyms]
(R,R)-Ts-DENEB
(R,R)-Ts-DENEB[R]
(R,R)-Ts-DENEB(regR)
N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II)
Chloro{N-[(1R,2R)-1,2-diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II)
Ruthenium(2+) chloride [(1R,2R)-2-({2-[(4-methylbenzyl)oxy]ethyl}amino)-1,2-diphenylethyl][(4-methylphenyl)sulfonyl]azanide (1:1:1)
Chloro{N-[(1R,2R)-1,2-diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II) (R,R)-Ts-DENEB(TM)
N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (R,R)-Ts-DENEB 1333981-84-2 | [Molecular Formula]
C31H33ClN2O3RuS | [MDL Number]
MFCD20922902 | [MOL File]
1333981-84-2.mol | [Molecular Weight]
645.16 |
| Chemical Properties | Back Directory | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
solid | [color ]
gray to brown | [Sensitive ]
air sensitive | [InChIKey]
INKUCOHLIHBSDN-ZAMYOOMVSA-M | [SMILES]
[Ru+2].[S](=O)(=O)([N-][C@@H]([C@H](NCCOCc4ccc(cc4)C)c3ccccc3)c2ccccc2)c1ccc(cc1)C.[Cl-] |
| Questions And Answer | Back Directory | [Reaction]
Catalyst used for asymmetric -transfer hydrogenation.
Catalyst used for asymmetric H2 – hydrogenation.
3. Catalyst used for dynamic kinetic resolution.
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| Hazard Information | Back Directory | [Uses]
(R,R)-Ts-DENEB (CAS# 1333981-84-2) is a catalyst used in asymmetric hydrogen transfer reactions, such as in the synthesis of 2-(1,2,3,4-tetrahydro-1-isoquinolyl)ethanol derivatives. (R,R)-Ts-DENEB is used to form hydrogen carrier systems, where the catalytic dehydrogenative coupling of methanol and 1,2-diamine is used to generate H2 without the production of CO2. | [reaction suitability]
reagent type: ligand |
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LaaJoo
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