| Identification | Back Directory | [Name]
(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS | [CAS]
850253-53-1 | [Synonyms]
(R)-DM-SEGPHOS
(R)-DM-SEGPHOS(R)
(R)-(+)-DM-SEGPHOS(regR)
(R)-(+)-DM-SEGPHOS®
(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole
(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS
1,1'-[(4R)-[4,4'-Bi-1,3-benzodioxole]-5,5'-diyl]bis[1,1-bis(3,5-dimethylphenyl)phosphine]
(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole, min. 98% (R)-(+)-DM-SEGPHOS(R)
[(4R)-(4,4μ-bi-1,3-benzodioxole)-5,5μ-diyl]bis[bis(3,5-dimethylphenyl)phosphine], (R)-(+)-5,5μ-Β:is[di(3,5-xylyl)phosphino]-4,4μ-bi-1,3-benzodioxole | [Molecular Formula]
C46H44O4P2 | [MDL Number]
MFCD09753008 | [MOL File]
850253-53-1.mol | [Molecular Weight]
722.8 |
| Chemical Properties | Back Directory | [Melting point ]
256-261 °C | [Boiling point ]
816.9±65.0 °C(Predicted) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Powder | [color ]
off white to pale yellow | [Optical Rotation]
[α]20/D +60, c = 0.1 in chloroform | [InChIKey]
XJJVPYMFHXMROQ-UHFFFAOYSA-N | [SMILES]
Cc1cc(C)cc(c1)P(c2cc(C)cc(C)c2)c3ccc4OCOc4c3-c5c6OCOc6ccc5P(c7cc(C)cc(C)c7)c8cc(C)cc(C)c8 |
| Questions And Answer | Back Directory | [Reaction]
- Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters.
- Copper catalyzed enantioselective [3 + 2] cycloaddition as a route to γ–amino ketones and 3-pyrrolidinones.
- Palladium catalyzed enantioselective addition of malonates to dihydroisoquinolines.
- Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
- Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone. See 44-0098 for Ru catalyst.
- Diastereoand enantioselective ruthenium-catalyzed hydrohydroxyalkylation of 2-silyl-butadienes.
- Asymmetric [2+2+2] cycloaddition.
- Linear selective C-H activation.
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