ChemicalBook--->CAS DataBase List--->13450-91-4

13450-91-4

13450-91-4 Structure

13450-91-4 Structure
IdentificationMore
[Name]

GALLIUM(III) IODIDE
[CAS]

13450-91-4
[Synonyms]

GALLIUM(III) IODIDE
GALLIUM IODIDE
GALLIUM TRIIODIDE
GaI3
Gallium iodide (GaI3)
galliumiodide(gai3)
GALLIUM(III) IODIDE, 99.99%
GALLIUM(III) IODIDE, ANHYDROUS, 99.999%
GALLIUM(III) IODIDE ANHYDROUS BEADS 9&
ultradry,99.999%(metalsbasis)
Gallium(III)iodide,anhydrous,99%
gallium(iii) iodide, ultra dry
Gallium(III) iodide, ultra dry, 99.999% (metals basis)
Gallium(III) iodide, anhydrous, 99%
[EINECS(EC#)]

236-611-6
[Molecular Formula]

GaI3
[MDL Number]

MFCD00016107
[Molecular Weight]

450.44
[MOL File]

13450-91-4.mol
Chemical PropertiesBack Directory
[Melting point ]

345 °C (subl.)(lit.)
[Boiling point ]

345°C
[density ]

4.15 g/mL at 25 °C(lit.)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2–8 °C
[solubility ]

Soluble in aromatic solvents.
[form ]

powder
[color ]

Yellow-green
[Specific Gravity]

4.15
[Water Solubility ]

Decomposes in water.
[Specific Heat Capacity]

Cp(crystal):0.222005J/(g·K),at 25℃
[Hydrolytic Sensitivity]

5: forms reversible hydrate
[Sensitive ]

Moisture Sensitive
[InChI]

InChI=1S/Ga.3HI/h;3*1H/q+3;;;/p-3
[InChIKey]

DWRNSCDYNYYYHT-UHFFFAOYSA-K
[SMILES]

[Ga](I)(I)I
[CAS DataBase Reference]

13450-91-4(CAS DataBase Reference)
[EPA Substance Registry System]

Gallium iodide (GaI3) (13450-91-4)
Hazard InformationBack Directory
[Chemical Properties]

-20 mesh with 99.999% purity; monoclinic; enthalpy of vaporization 56.5 kJ/mol; enthalpy of fusion 16.30kJ/mol; can be prepared by direct reaction of Ga and I2 [CRC10] [CER91] [KIR78]
[Uses]

Gallium(III) iodide is widely used as lewis acid, a precursor of organogallium reagents. It can also be involved in detection of solar neutrinos.
[reaction suitability]

reagent type: catalyst
core: gallium
Safety DataBack Directory
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
R42/43:May cause sensitization by inhalation and skin contact .
R63:Possible risk of harm to the unborn child.
[Safety Statements ]

S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3260 8/PG 2
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

II
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Eye Dam. 1
Repr. 2
Skin Corr. 1B
Skin Sens. 1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Gallium(III) iodide, ultra dry, 99.999% (metals basis)(13450-91-4)
[Sigma Aldrich]

13450-91-4(sigmaaldrich)
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