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13451-08-6

13451-08-6 Structure

13451-08-6 Structure
IdentificationBack Directory
[Name]

Sulfur tetrachloride
[CAS]

13451-08-6
[Synonyms]

Sulfur tetrachloride
sulphur tetrachloride
[Molecular Formula]

Cl4S
[MOL File]

13451-08-6.mol
[Molecular Weight]

173.877
Chemical PropertiesBack Directory
[form ]

off-white solid
Safety DataBack Directory
[Symbol(GHS) ]


GHS05,GHS09
[Signal word ]

Danger
[Hazard statements ]

H314-H400
[Precautionary statements ]

P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501-P273-P391-P501
[Hazard Codes ]

C,N
[Risk Statements ]

14-34-50
[Safety Statements ]

26-45-61
Questions and Answers (Q&A)Back Directory
[Description]

The main use of sulfur tetrachloride is to provide fluoride to compounds with hydroxyl and carbonyl functional groups, producing corresponding fluorocarbons. This reaction is useful for making water- and oil- repelling materials for polymers, and in producing high-lubricity elastomers, with some applications in pharmaceuticals and herbicides. 
As a highly corrosive gas, it is difficult to handle, and this application is being phased out in favor of reactions utilizing diethylaminosulfur trifluoride. This compound however is produced using sulfur tetrachloride, which is prepared using sulfur tetrachloride.
[References]

https://en.wikipedia.org/wiki/Fluorocarbon
https://en.wikipedia.org/wiki/Sulfur_tetrafluoride
https://toxnet.nlm.nih.gov/cgi-bin/sis/search2/r?dbs+hsdb:@term+@rn+@rel+7783-60-0
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