ChemicalBook--->CAS DataBase List--->13462-90-3

13462-90-3

13462-90-3 Structure

13462-90-3 Structure
IdentificationMore
[Name]

NICKEL IODIDE
[CAS]

13462-90-3
[Synonyms]

NICKEL(II) IODIDE
NICKEL IODIDE
NICKEL IODIDE (OUS)
nickel(2+)iodide
nickeldiiodide
nickeliodide(nii2)
nickeliodide(nii2)[qr]
nickelousiodide
NICKEL(II) IODIDE, ANHYDROUS, POWDER, 99.99%
NICKEL(II) IODIDE, POWDER
Nickeliodide,anhydrous,99.5%(metalsbasis)
Nichel((Ⅱ)idide hexahydrate
Nickel(II)iodide,anhydrous(99.5%-Ni)
nickel(ii) iodide, anhydrous
nickel(ii) iodide, ultra dry
Nickel Iodide, Anhydrous
Nickel(II) iodide, anhydrous, 99.5% (metals basis)
Nickel(II) iodide, ultra dry, 99.99% (metals basis)
Diiodonickel(II)
Nickel(II) diiodide
[EINECS(EC#)]

236-666-6
[Molecular Formula]

I2Ni
[MDL Number]

MFCD00016264
[Molecular Weight]

312.5
[MOL File]

13462-90-3.mol
Chemical PropertiesBack Directory
[Appearance]

Black, crystalline powder or blue-green crystals; hygroscopic.Soluble in alcohol and water.
[Melting point ]

797 °C(lit.)
[Boiling point ]

sublimes [LID94]
[density ]

5.83 g/mL at 25 °C(lit.)
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[solubility ]

H2O: slightly soluble(lit.)
[form ]

powder
[color ]

black
[Specific Gravity]

5.834
[Water Solubility ]

Soluble in water and alcohols.
[Sensitive ]

Hygroscopic
[Merck ]

13,6535
[Exposure limits]

ACGIH: TWA 0.1 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
[Stability:]

hygroscopic
[Major Application]

battery manufacturing
[InChI]

1S/2HI.Ni/h2*1H;/q;;+2/p-2
[InChIKey]

BFSQJYRFLQUZKX-UHFFFAOYSA-L
[SMILES]

I[Ni]I
[CAS DataBase Reference]

13462-90-3(CAS DataBase Reference)
[EPA Substance Registry System]

Nickel iodide (NiI2) (13462-90-3)
Hazard InformationBack Directory
[Chemical Properties]

Black, crystalline powder or blue-green crystals; hygroscopic.Soluble in alcohol and water.
[Uses]

Strongly accelerates Sml2 mediated homocoupling of imines into vicinal diamines and heterocoupling reactions between imines and ketones.1
[Hazard]

Toxic by ingestion.
[Preparation]

Nickel iodide can be prepared by dehydration of the hexahydrate or by the metathetic reaction between sodium iodide and nickel(II) chloride or nitrate in ethanol. It has the CdCl2 type lattice and is paramagnetic down to 75°K. Only one hydrate is well characterized—the blue-green NiI2?6H20 ; unlike the other halide hexahydrates, this contains [Ni(H2O)6]2+ cations.
[reaction suitability]

reagent type: catalyst
core: nickel
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H317-H350-H360
[Precautionary statements ]

P201-P280-P302+P352-P308+P313
[Hazard Codes ]

T
[Risk Statements ]

R45:May cause cancer.
R61:May cause harm to the unborn child.
R42/43:May cause sensitization by inhalation and skin contact .
[Safety Statements ]

S53:Avoid exposure-obtain special instruction before use .
S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3260 8/PG 2
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[HS Code ]

2827600090
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Aquatic Acute 1
Aquatic Chronic 1
Carc. 1A Inhalation
Muta. 2
Repr. 1B
Resp. Sens. 1
Skin Sens. 1
STOT RE 1 Inhalation
[Hazardous Substances Data]

13462-90-3(Hazardous Substances Data)
Spectrum DetailBack Directory
[Spectrum Detail]

NICKEL IODIDE(13462-90-3)IR1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Nickel(II) iodide, ultra dry, 99.99% (metals basis)(13462-90-3)
[Sigma Aldrich]

13462-90-3(sigmaaldrich)
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