| Identification | More | [Name]
o-Anisaldehyde | [CAS]
135-02-4 | [Synonyms]
2-ANISALDEHYDE
2-METHOXYBENZALDEHYDE
AKOS BBS-00003204
ANISALDEHYDE,2-
O-ANISALDEHYDE
O-METHOXYBENZALDEHYDE
SALICYLALDEHYDE METHYL ETHER
2-methoxy-benzaldehyd
2-Methoxybenzenecarboxaldehyde
6-Methoxybenzaldehyde
Benzaldehyde, o-methoxy-
Benzaldehyde,2-methoxy-
2-Methoxybenzaldehyde/o-Anisadehyde
MethoxybenzaldehydeAnisaldehyd
ortho-anisaldehyde
O-ANISALDEHYDE 97+%
2-Methoxybenzaldehyde, 98% (2-Anisaldehyd)
2-METHOXYBENZALDEHYDE (O-METHOXYBENZALDEHYDE)
ANISALDEHYDE,2-(RG)
2-Methoxybenzaldehyde (o-Anisaldehyde) | [EINECS(EC#)]
205-171-7 | [Molecular Formula]
C8H8O2 | [MDL Number]
MFCD00003308 | [Molecular Weight]
136.15 | [MOL File]
135-02-4.mol |
| Chemical Properties | Back Directory | [Appearance]
light yellow to pale brown | [Melting point ]
34-40 °C(lit.)
| [Boiling point ]
238 °C(lit.)
| [density ]
1.127 g/mL at 25 °C(lit.)
| [FEMA ]
4077 | [refractive index ]
1.5608
| [Fp ]
244 °F
| [storage temp. ]
2-8°C | [solubility ]
Solubility Slightly soluble in water; soluble in ethanol | [form ]
Low Melting Crystalline Mass | [color ]
Light yellow to pale brown | [Specific Gravity]
1.127 | [Odor]
at 10.00 % in propylene glycol. sweet powdery hawthorn guaiacol vanilla acetophenone almond | [PH Range]
Non1 uorescence (3.1) to green 1 uorescence (4.4) | [biological source]
synthetic | [Odor Type]
anisic | [Water Solubility ]
insoluble | [Sensitive ]
Air Sensitive | [JECFA Number]
2062 | [BRN ]
606301 | [Henry's Law Constant]
1.0×101 mol/(m3Pa) at 25℃, Ji et al. (2008) | [Major Application]
Battery, hair dyes, bird repellents, cosmetics, antibacterial, antipyretic | [Cosmetics Ingredients Functions]
PERFUMING | [InChI]
1S/C8H8O2/c1-10-8-5-3-2-4-7(8)6-9/h2-6H,1H3 | [InChIKey]
PKZJLOCLABXVMC-UHFFFAOYSA-N | [SMILES]
[H]C(=O)c1ccccc1OC | [LogP]
1.72 | [Uses]
Intermediate. | [CAS DataBase Reference]
135-02-4(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzaldehyde, 2-methoxy-(135-02-4) | [Storage Precautions]
Air sensitive;Store under inert gas | [EPA Substance Registry System]
135-02-4(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P264-P271-P280-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R36/38:Irritating to eyes and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
2
| [RTECS ]
BZ2610000
| [F ]
9-23 | [TSCA ]
Yes | [HS Code ]
29124900 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 | [Safety Profile]
Moderately toxic by
ingestion. A skin irritant. Mutation data
reported. Combustible liquid. When heated
to decomposition it emits acrid smoke and
irritating fumes. | [Toxicity]
LD50 orally in Rabbit: 2500 mg/kg LD50 dermal Rabbit > 5000 mg/kg |
| Questions And Answer | Back Directory | [Description]
O-Anisaldehyde (also 2-methoxybenzaldehyde) is found in cassia oil, cinnamon bark, and cinnamon bark oil. It is a clear colorless liquid with a strong aroma.
O-Anisaldehyde is used as a flavor agent in foods including nonalcoholic/alcoholic beverages, baked goods, chewing gum, confections, frozen dairy, fruit ices, hard/soft candy, instant coffee, tea, Jams, jellies, and milk products. O-Anisaldehyde has been used to examine the acaricidal activity of Periploca sepium oil and its active component against Tyrophagus and to obtain good enantioselectivities using Cu(OAc)(2)-bis(oxazolines) via hydrogen bonding in asymmetric Henry reaction.
| [References]
[1] George A. Burdock (2016) Fenraoli’s Handbook of Flavor Ingredients, Sixth Edition.
[2] https://www.alfa.com/en/catalog/A10770/
|
| Hazard Information | Back Directory | [Chemical Properties]
Colorless to cream amber crystalline powder; sweet powdery hawthorn guaiacol vanilla acetophenone almond aroma. | [Chemical Properties]
light yellow to pale brown | [Occurrence]
Reported found in Cassia oil, cinnamon bark, and Cinnamon bark oil (Cinnamomum zeylanicum Blume), Sri
Lanka (0.09–0.15%) | [Definition]
ChEBI: 2-Methoxybenzaldehyde is a carbonyl compound. | [Aroma threshold values]
Medium strength odor; anisic type; recommend smelling in a 10.00% solution or less.
| [Taste threshold values]
Sweet powdery guaiacol musty vanilla floral almond taste at 50 ppm in water. | [Synthesis Reference(s)]
Journal of Heterocyclic Chemistry, 11, p. 943, 1974 DOI: 10.1002/jhet.5570110616
Tetrahedron Letters, 25, p. 1843, 1984 DOI: 10.1016/S0040-4039(01)90056-5 | [Biochem/physiol Actions]
Naturally-occurring aromatic aldehyde with acaricidal activity. May condense with L-tryptophan in foods to form the corresponding phenolic tetrahydro-β-carboline-3-carboxylic acid which is a potent antioxidant. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
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