| Identification | Back Directory | [Name]
MOLYBDENUM(VI) DICHLORIDE DIOXIDE | [CAS]
13637-68-8 | [Synonyms]
MoO2Cl2
Molybdenum chloride oxide
MOLYBDENUM DIOXY DICHLORIDE
MOLYBDENUM DICHLORIDE OXIDE
Dichlorodioxomolybdenum(VI)
MOLYBDENUM DICHLORIDE DIOXIDE
dioxomolybdenum(2+):dichloride
MOLYBDENUM(VI) DICHLORIDE DIOXIDE
Molybdenum dichloride dioxide, Cl 34% min
Molybdenum chlorideoxide (MoCl2O2), (T-4)- (9CI) | [Molecular Formula]
Cl2MoO2 | [MDL Number]
MFCD00014225 | [MOL File]
13637-68-8.mol | [Molecular Weight]
198.84 |
| Chemical Properties | Back Directory | [Melting point ]
184(subl.) | [density ]
3.31 g/mL at 25 °C(lit.)
| [solubility ]
reacts with H2O | [form ]
yellow-orange solid | [color ]
yellow-orange | [InChI]
InChI=1S/2ClH.Mo.2O/h2*1H;;;/q;;+2;;/p-2 | [InChIKey]
JCFNAADCQWXIJD-UHFFFAOYSA-L | [SMILES]
[Mo](Cl)(Cl)(=O)=O |
| Hazard Information | Back Directory | [Chemical Properties]
yellowish-orange solid [LID94] | [Uses]
Molybdenum(VI) Dichloride Dioxide can be used as electrolytes for secondary lithium batteries. |
| Questions And Answer | Back Directory | [Description]
Molybdenum is much less toxic than typical heavy metals and already found application as an alternative substitute for some heavy metals. Molybdenum has also found application in materials like pigments, corrosion inhibitors, smoke suppressants, lubricants and fertilizers. Molybdenum dichloride dioxide has strong application as a kind of catalyst in organic transformation. Molybdenum Dichloride Dioxide can be used to catalyze carbamate formation from an alcohol and isocyanates, acylation reactions, thioglycosylation of functionalized peracetylated glycosides, hydrosilylation of aldehydes and ketones as well as reduction of many compounds like imines, esters, amides and N-oxides. It is also used to catalyze the oxidation of sulfides, thiols as well as the synthesis of beta-keto esters and thiocaetalization of aldehydes. It can also be used to analyze the antioxidant in solder plating solutions.
| [Reference]
- Stock, C., & Brückner, R. (2010) Synlett, 2010(16), 2429-2434.
- KING, Mackenzie, SCHOMBURG, Cory, HILGARTH, & Monica. (2005). Analysis of antioxidant in solder plating solutions using molybdenum dichloride dioxide.
- Jeyakumar, Kandasamy, and D. K. Chand. Journal of Chemical Sciences 121.2(2009):111-123.
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| Company Name: |
Henan Jiuke Chemical Co. LTD Gold
|
| Telephone: |
0370-2071226 17303700913 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList1506642/0_EN.htm |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Rhawn Reagent
|
| Telephone: |
400-400-1332688 18019345275 |
| Website: |
http://www.rhawn.cn |
|