ChemicalBook--->CAS DataBase List--->13680-35-8

13680-35-8

13680-35-8 Structure

13680-35-8 Structure
IdentificationMore
[Name]

4,4'-Methylenebis(2,6-diethylaniline)
[CAS]

13680-35-8
[Synonyms]

4,4'-METHYLENEBIS(2,6-DIETHYLANILINE)
LABOTEST-BB LT00053356
LONZACURE(R) M-DEA
M-DEA
4,4’-methylenebis[2,6-diethyl-benzenamin
4,4’-methylenebis[2,6-diethyl-Benzenamine
4,4'-Methylene-(Bis(2,6-Diethylaniline) (MDEA)
4,4'-METHYLENEBIS(2,6-DIETHYLANILINE), 9 9%
Benzenamine, 4,4-methylenebis2,6-diethyl-
4,4''-METHYLENEBIS(2,6-DIETHYLANILINE),=99%(HPLC)
4,4'-Diamino-3,3',5,5'-tetraethyldiphenylmethane
Bis(4-amino-3,5-diethylphenyl)methane
2,2',6,6'-Tetraethyl(4,4'-methylenedianiline)
[EINECS(EC#)]

237-185-4
[Molecular Formula]

C21H30N2
[MDL Number]

MFCD00071552
[Molecular Weight]

310.48
[MOL File]

13680-35-8.mol
Chemical PropertiesBack Directory
[Appearance]

Crystalline Powder
[Melting point ]

88-90 °C(lit.)
[Boiling point ]

205 °C / 0.5mmHg
[density ]

0.90
[vapor pressure ]

0Pa at 25℃
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[solubility ]

soluble in Toluene
[form ]

powder to crystal
[pka]

4.88±0.25(Predicted)
[color ]

White to Almost white
[Water Solubility ]

440μg/L at 20℃
[Usage]

LONZACURE(R) M-DEA is an excellent chain extender for polyurethanes (PU) and also a curing agent for epoxides (EP). It provides improved mechanical and dynamic properties which cannot be achieved with standard formulations.
[InChI]

InChI=1S/C21H30N2/c1-5-16-10-14(11-17(6-2)20(16)22)9-15-12-18(7-3)21(23)19(8-4)13-15/h10-13H,5-9,22-23H2,1-4H3
[InChIKey]

NWIVYGKSHSJHEF-UHFFFAOYSA-N
[SMILES]

C(C1=CC(CC)=C(N)C(CC)=C1)C1=CC(CC)=C(N)C(CC)=C1
[LogP]

4.29 at 25℃
[CAS DataBase Reference]

13680-35-8(CAS DataBase Reference)
[EPA Substance Registry System]

13680-35-8(EPA Substance)
Questions And AnswerBack Directory
[Preparation]

2,6-Diethylaniline (DEA) raw material was dissolved in water, and a certain amount of hydrochloric acid was added to generate 2,6-diethylaniline hydrochloride. Then, a proportional amount of formaldehyde aqueous solution was added dropwise, and the mixture was heated to carry out a condensation reaction. After the reaction was maintained at this temperature, the mixture was neutralized with an alkaline solution to precipitate crude MDEA. This crude MDEA was then decolorized, dehydrated, crystallized, and granulated to obtain 4,4′-methylene-bis-(2,6-diethylaniline).

Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P264-P270-P301+P312-P302+P352-P305+P351+P338
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HS Code ]

29215900
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

4,4'-Methylenebis(2,6-diethylaniline)(13680-35-8).msds
Hazard InformationBack Directory
[Chemical Properties]

Crystalline Powder
[Uses]

LONZACURE(R) M-DEA is an excellent chain extender for polyurethanes (PU) and also a curing agent for epoxides (EP). It provides improved mechanical and dynamic properties which cannot be achieved with standard formulations.
[Flammability and Explosibility]

Notclassified
Spectrum DetailBack Directory
[Spectrum Detail]

4,4'-Methylenebis(2,6-diethylaniline)(13680-35-8)1HNMR
4,4'-Methylenebis(2,6-diethylaniline)(13680-35-8)FT-IR
4,4'-Methylenebis(2,6-diethylaniline)(13680-35-8)IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

13680-35-8(sigmaaldrich)
[TCI AMERICA]

4,4'-Methylenebis(2,6-diethylaniline),>97.0%(GC)(T)(13680-35-8)
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