| Identification | Back Directory | [Name]
(R)-DM-BINAP | [CAS]
137219-86-4 | [Synonyms]
Xylbinap
(R)-DM-BINAP
RAC-XYLYL-BINAP
(R)-Xylyl-BINAP
98% (R)-XylBINAP
(R)-(+)-XylBINAP
(R)-3,5-Xyl-BINAP
(R)-3,5-XYLYL-BINAP
2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
(r)-(+)-2,2'-bis(di(3,5-xylyl)phosphino)-1,1'-binaphthy
(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
RACEMIC-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL
2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL
(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%
(R)-(+)-2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL
(R)-(+)-2,2'-bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl
(R)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,(R)-XylBINAP
(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl, 98% (R)-(+)-XylBINAP
(R)-(+)-2,2''-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1''-BINAPHTHYL (R)-3,5-XYLYL-BINAP
(R)-(+)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,98%(R)-3,5-xylyl-BINAP
(R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-B
1,1'-[(1R)-[1,1'-binaphthalene]-2,2'-diyl]bis[1,1-bis(3,5-dimethylphenyl)-Phosphine
(R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, ((R)-Xylyl-BINAP)
(R)-(+)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl, 98%((R)-Xylyl-BINAP)
PHOSPHINE, 1,1''-[(1R)-[1,1''-BINAPHTHALENE]-2,2''-DIYL]BIS[1,1-BIS(3,5-DIMETHYLPHENYL)-
(R)-(+)-2,2μ-Bis[di(3,5-xylyl)phosphino]-1,1μ-binaphthyl, (R)-(+)-1,1μ-Binaphthalene-2,2μ-diyl)bis[bis(3,5-dimethylphenyl)phosphine] | [EINECS(EC#)]
1312995-182-4 | [Molecular Formula]
C52H48P2 | [MDL Number]
MFCD01630821 | [MOL File]
137219-86-4.mol | [Molecular Weight]
734.89 |
| Chemical Properties | Back Directory | [Melting point ]
203-206°C | [alpha ]
169 º (c=1 in chloroform) | [Boiling point ]
825.3±65.0 °C(Predicted) | [storage temp. ]
Inert atmosphere,Room Temperature | [Water Solubility ]
Insoluble in water | [form ]
crystal | [color ]
white to pale yellow | [Optical Rotation]
[α]20/D +169°, c = 1 in chloroform | [InChIKey]
MXGXXBYVDMVJAO-UHFFFAOYSA-N | [SMILES]
C1(C2=C3C(C=CC=C3)=CC=C2P(C2=CC(C)=CC(C)=C2)C2=CC(C)=CC(C)=C2)=C2C(C=CC=C2)=CC=C1P(C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1 |
| Questions And Answer | Back Directory | [Reaction]
- Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
- Ligand used in the enantioselective fluorination of oxindoles.
- Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
- Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
- Asymmetric hydroboration of unsaturated imines.
|
| Hazard Information | Back Directory | [Uses]
(R)-(+)-XylBINAP is a phosphine-based ligand used in the preparation of various catalysts, such as Pd catalysts for the asymmetric dearomative alkenylation of indoles through a reductive-?Heck reaction. | [Uses]
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LaaJoo Gold
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