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100165-88-6

100165-88-6 Structure

100165-88-6 Structure
IdentificationMore
[Name]

(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
[CAS]

100165-88-6
[Synonyms]

(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)1,1-BINAPHTHYL
(R)-TOL-BINAP
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
(S)-TOL-BINAP
BisdiptolylphosphinobinaphthylSTolBI
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, (S)-p-Tol-BINAP
(S)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-&
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, 98+%
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl,98%(S)-Tol-BINAP
(S)-(-)-2,2''-BIS(DI-P-TOLYLPHOSPHINO)-1,1''-BINAPHTHYL (S)-TOL-BINAP
(S)-(-)-2,2''-Bis-[bis-(p-tolylphosphino)]-1,1''-binaphthyl
PHOSPHINE, 1,1''-(1S)-[1,1''-BINAPHTHALENE]-2,2''-DIYLBIS[1,1-BIS(4-METHYLPHENYL)-
(S)-T-BINAP
(S)-Tol-BINAP, (S)-(-)-2,2μ-p-tolyl-phosphino)-1,1μ-binaphthyl
[Molecular Formula]

C48H40P2
[MDL Number]

MFCD00269856
[Molecular Weight]

678.78
[MOL File]

100165-88-6.mol
Chemical PropertiesBack Directory
[Appearance]

White powder
[mp ]

252-256 °C
[CAS DataBase Reference]

100165-88-6(CAS DataBase Reference)
[Storage Precautions]

Air sensitive;Moisture sensitive;Store under inert gas
[Storage Precautions]

Store under inert gas;Moisture sensitive;Air sensitive
Safety DataBack Directory
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
[HS Code ]

29333990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Etanol-->Ethyl acetate-->Tetrahydrofuran-->Sodium-->N,N-Dimethylformamide-->Toluene-->Triethylamine-->Azabenzene-->Magnesium-->Triphenylphosphine-->1,2-Dichloroethane -->Diethyl phosphite-->Nickel(II) chloride hexahydrate-->4-Bromotoluene-->Triethylenediamine-->(R)-(+)-1,1'-Bi-2-naphthol-->Trifluoromethanesulfonic anhydride-->Trichlorosilane-->(S)-(-)-1,1'-Bi-2-naphthol
Questions And AnswerBack Directory
[Reaction]

  1. Useful ligand for palladium-catalyzed carbon-oxygen bond formation.
  2. Ligand for palladium-catalyzed α-arylation of ketones.
  3. Ligand for Cu-catalyzed asymmetric conjugate reduction.
  4. Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.
  5. Enantioselective conjugate reduction of lactones and lactams.
  6. Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.
  7. Catalytic Aldol reaction to ketones.
  8. Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.
  9. Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.
  10. Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.
  11. Rhodium-catalyzed cross cyclotrimerization.



Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, 98+%(100165-88-6)
[Alfa Aesar]

(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, 98%(100165-88-6)
[Sigma Aldrich]

100165-88-6(sigmaaldrich)
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