| Identification | More | [Name]
COBALT(II) FLUORIDE TETRAHYDRATE | [CAS]
13817-37-3 | [Synonyms]
COBALT(II) FLUORIDE
COBALT(II) FLUORIDE TETRAHYDRATE
COBALTOUS FLUORIDE 4H2O
Cobaltfluoridetetrahydrate
COBALT(II) FLUORIDE TETRAHYDRATE, 99.99%
cobalt(ii) fluoride tetrahydrate, puratronic
Cobalt(II) fluoride tetrahydrate, Puratronic(R), 99.99% (metals basis)
Cobalt (II) fluoride tetrhydrate
Cobalt(II) fluoride tetrahydrate, Puratronic, 99.99% (metals basis) | [EINECS(EC#)]
233-061-9 | [Molecular Formula]
CoF2H8O4 | [MDL Number]
MFCD00149656 | [Molecular Weight]
168.99 | [MOL File]
13817-37-3.mol |
| Chemical Properties | Back Directory | [Appearance]
Rose red crystal | [Melting point ]
200°C | [Boiling point ]
decomposes [MER06] | [density ]
2.19 g/mL at 25 °C(lit.)
| [solubility ]
water: solubleslightly | [form ]
Powder | [color ]
Pink | [Specific Gravity]
2.19 | [Water Solubility ]
soluble H2O [MER06] | [Sensitive ]
Moisture Sensitive | [Merck ]
14,2440 | [Exposure limits]
ACGIH: TWA 0.02 mg/m3 | [Major Application]
(Catalyst) | [InChI]
1S/Co.2FH.4H2O/h;2*1H;4*1H2/q+2;;;;;;/p-2 | [InChIKey]
MNHUTFNEBYCZAF-UHFFFAOYSA-L | [SMILES]
O.O.O.O.F[Co]F | [CAS DataBase Reference]
13817-37-3(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Chemical Properties]
Rose red crystal | [Uses]
Cobalt(II) fluoride tetrahydrate is used as a starting material to synthesize 2-dimensional cobalt-fluoride-oxide as an oxygen evolution electrocatalysts using a rapid thermal annealing (RTA) method. In this process, the cobalt(II) fluoride tetrahydrate is placed in an alumina furnace at 400°C. After annealing for 20 minutes in air, the alumina crucible is removed and allowed to cool naturally to room temperature. The resulting products are then rinsed multiple times in deionized water and ethanol to remove any soluble impurities. Finally, the product is dried thoroughly in a vacuum oven at 60°C to obtain the 2D nanosheets sample. Furthermore, when combined with N-Heterocyclic Carbenes, Cobalt(II) fluoride tetrahydrate has been found to be highly effective as a catalyst for cross-coupling reactions between aryl Grignard reagents and aryl as well as heteroaryl halides. This reaction results in the formation of unsymmetrical biaryls. | [Synthesis]
Weigh 22.5gCoCl3·6H2O dissolved in 60ml distilled water, heated to 40 ~ 50 ℃, stirring dropwise addition of 30gNa2CO3·10H2O dissolved in 25ml distilled water hot solution, immediately reacted to get the rose-red CoCO3. aging 2h after filt |
| Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R32:Contact with acids liberates very toxic gas.
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2923 8/PG 3
| [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
III | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Eye Dam. 1
Skin Corr. 1B |
|
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
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