ChemicalBook--->CAS DataBase List--->14044-63-4

14044-63-4

14044-63-4 Structure

14044-63-4 Structure
IdentificationBack Directory
[Name]

BUT-3-YN-1-AMINE
[CAS]

14044-63-4
[Synonyms]

3-ButynylaMine
3-Butyn-1-amine
BUT-3-YNYLAMINE
1-AMino-3-butyne
BUT-3-YN-1-AMINE
4-Amino-1-butyne
1-AMino-3-butyne 95%
3-Butyn-1-amine (9CI)
3-BUTYNYLAMINE, 97%3-BUTYNYLAMINE, 97%3-BUTYNYLAMINE, 97%3-BUTYNYLAMINE, 97%
[Molecular Formula]

C4H7N
[MDL Number]

MFCD09997741
[MOL File]

14044-63-4.mol
[Molecular Weight]

69.11
Chemical PropertiesBack Directory
[Boiling point ]

105℃
[density ]

0.844 g/mL at 25 °C
[refractive index ]

1.4438 (20℃)
[Fp ]

10℃
[storage temp. ]

2-8°C
[pka]

8.86±0.10(Predicted)
Safety DataBack Directory
[Hazard Codes ]

F,C
[Risk Statements ]

11-22-34
[Safety Statements ]

26-36/37/39-45
[RIDADR ]

UN 2733 3/PG 2
[WGK Germany ]

3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Carbamic acid, N-3-butyn-1-yl-, ethyl ester-->AMINOMETHYLATING REAGENT A-->N-(3-BUTYNYL)PHTHALIMIDE-->3-BUTYN-1-AMINE HYDROCHLORIDE-->3-Butynyl Methanesulfonate-->SODIUM ACETYLIDE-->3-Bromopropyne-->Acetylene-->2-Bromoethylamine hydrobromide
Hazard InformationBack Directory
[Uses]

1-Amino-3-butyne, a bifunctional linker can be used:
  • In Buchwald–Hartwig amination reaction of 1,2,3,4-tetrahydroacridine trifluoromethanesulfonate derivative.
  • As a reagent to synthesize dialkynylamides from diacids.
  • For the post-polymerization modification of poly(2-alkyl/aryl-2-oxazoline)s (PAOx) polymer by amidation of its methyl ester side chains.
  • As a crosslinker which can bind with resin as well as nanocrystalline cellulose to facilitate the terminal alkyne group for further functionalizations.

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