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14098-24-9

14098-24-9 Structure

14098-24-9 Structure
IdentificationMore
[Name]

Benzo-18-crown-6
[CAS]

14098-24-9
[Synonyms]

1,4,7,10,13,16-HEXAHYDROXY-16-ORTHOCYCLOPHANE
2,3,5,6,8,9,11,12,14,15-DECAHYDRO-1,4,7,10,13,16-BENZOHEXAOXACYCLOOCTADECIN
2,3-BENZO-1,4,7,10,13,16-HEXAOXAOCTADEC-2-ENE
BENZO-18-CROWN-6
BENZO-18-CROWN 6-ETHER
CROWN ETHER/BENZO-18-CROWN-6
4,7,10,13,16-Benzophexaoxacyclooctadecin,,3,5,6,8,9,11,12,14,15-decahydro-1
BENZO-18-CROWN-6 99+%
1,4,7,10,13,16-Benzohexaoxacyclooctadecin, 2,3,5,6,8,9,11,12,14,15-decahydro-
2,3,5,6,8,9,11,12, 14,15-decahydro-1,4,7,10,13,16-Benzophexaoxacyclooctadecin
1,14-(1,2-Phenylenebisoxy)-3,6,9,12-tetraoxatetradecane
1,2-[Ethylenebis(oxyethyleneoxyethyleneoxy)]benzene
1,2-[Ethylenebisoxybis(ethyleneoxyethyleneoxy)]benzene
1,2-Ethylenebis(oxyethyleneoxyethyleneoxy)benzene
[EINECS(EC#)]

604-215-6
[Molecular Formula]

C16H24O6
[MDL Number]

MFCD00062741
[Molecular Weight]

312.36
[MOL File]

14098-24-9.mol
Chemical PropertiesBack Directory
[Appearance]

white granular powder and chunks
[Melting point ]

42-45 °C (lit.)
[Boiling point ]

412.28°C (rough estimate)
[density ]

1.1858 (rough estimate)
[refractive index ]

1.4795 (estimate)
[Fp ]

>230 °F
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Liquid
[color ]

Clear colorless
[Sensitive ]

Hygroscopic
[BRN ]

1626123
[CAS DataBase Reference]

14098-24-9(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi,Xn
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[F ]

3
[HazardClass ]

IRRITANT
[HS Code ]

29329990
Hazard InformationBack Directory
[Chemical Properties]

white granular powder and chunks
[Purification Methods]

Purify it by passage through a DEAE cellulose column in cyclohexane. It recrystallises from n-hexane. Its thiourea complex has m 127o [5-6 mol of urea to ether, Pedersen J Org Chem 36 1690 1971]. The stability constants of the Na+, K+, Rb+, Cs+, Tl+ and Ba2+ complexes are described in Hofmanova et al. Inorg Chim Acta 28 73 1978. [NMR: Live & Chan J Am Chem Soc 98 3769 1976]. [Beilstein 19/12 V 618.] IRRITANT.
Spectrum DetailBack Directory
[Spectrum Detail]

Benzo-18-crown-6(14098-24-9)MS
Benzo-18-crown-6(14098-24-9)1HNMR
Benzo-18-crown-6(14098-24-9)13CNMR
Benzo-18-crown-6(14098-24-9)IR1
Benzo-18-crown-6(14098-24-9)IR2
Benzo-18-crown-6(14098-24-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Benzo-18-crown-6, 97%(14098-24-9)
[Alfa Aesar]

Benzo-18-crown-6, 98%(14098-24-9)
[Sigma Aldrich]

14098-24-9(sigmaaldrich)
[TCI AMERICA]

Benzo-18-crown 6-Ether,>98.0%(GC)(14098-24-9)
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