| Identification | More | [Name]
TRANS-STILBENE OXIDE | [CAS]
1439-07-2 | [Synonyms]
1,2-DIPHENYLETHYLENE OXIDE
1,2-DIPHENYL-ETHYLENOXIDE
TRANS-1,2-DIPHENYL-ETHYLENOXIDE
TRANS-1,2-DIPHENYLOXIRANE
TRANS-2,3-DIPHENYLETHYLENE OXIDE
TRANS-2,3-DIPHENYLOXIRANE
TRANS-STILBENE OXIDE
3-diphenyl-trans-oxiran
alpha’-epoxy-alphtrans-bibenzy
Bibenzyl, alpha,alpha'-epoxy-, trans-
Oxirane, 2,3-diphenyl-, trans-
Oxirane,trans-2,3-diphenyl-
trans-alpha,alpha’-epoxybibenzyl
trans-Stilbene epoxide
trans-stilbeneepoxide
TSO
trans-alpha,alpha-epoxydibenzyl
trans-1,2-Diphenylethylene oxide
trans-Stilbene oxide, trans-1,2-Diphenyloxirane
trans-Stibene oxide | [EINECS(EC#)]
215-877-7 | [Molecular Formula]
C14H12O | [MDL Number]
MFCD00064311 | [Molecular Weight]
196.24 | [MOL File]
1439-07-2.mol |
| Questions And Answer | Back Directory | [Synthesis]
To a magnetically stirred solution of trans-stilbene (0.724 g, 4.02 mmol) in 5 mL of acetone in a 125-mL stoppered Erlenmeyer flflask was added a solution of DMDO in acetone (0.062 M, 66 mL, 4.09 mmol) at room temperature (about 20 °C). The progress of the reaction was followed by GLC analysis, which indicated that transstilbene was converted into the oxide in 6 h. Removal of the excess acetone on a rotary evaporator (20 °C, 15 mm Hg) afforded a white crystalline solid. The solid was dissolved in CH2Cl2 (30 mL) and dried over anhydrous Na2SO4. The drying agent was removed by fifiltration and washed with CH2Cl2. The solution was concentrated on a rotary evaporator, and the remaining solvent was removed (20 °C, 15 mmHg) to give an analytically pure sample of the oxide (0.788 g, 100%).
Reference: Murray, R. W.; Singh M. Org. Syn. 1998, Collective Volume 9, 288−293. |
| Safety Data | Back Directory | [Hazard Codes ]
F | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [RTECS ]
DT4391500
| [Hazard Note ]
Flammable | [HS Code ]
29109000 |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Uses]
trans-Stilbene Oxide is used in preparation method of metal complex covalent organic framework material. | [Definition]
ChEBI: R-trans-stilbene oxide is a trans-stilbene oxide. It is an enantiomer of a S-trans-stilbene oxide. |
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