| Identification | More | [Name]
2-[N,N-BIS(TRIFLUOROMETHANESULFONYL)AMINO]-5-CHLOROPYRIDINE | [CAS]
145100-51-2 | [Synonyms]
2-[N,N-BIS(TRIFLUOROMETHANESULFONYL)AMINO]-5-CHLOROPYRIDINE
2-[N,N-BIS(TRIFLUOROMETHANESULPHONYL)AMINO]-5-CHLOROPYRIDINE
2-[N,N-BIS(TRIFLUOROMETHYLSULFONYL)AMINO]-5-CHLOROPYRIDINE
2-[N,N-BIS(TRIFLUOROMETHYLSULPHONYL)AMINO]-5-CHLOROPYRIDINE
N-(5-CHLORO-2-PYRIDYL)BIS(TRIFLUOROMETHANESULFONIMIDE)
N-(5-CHLORO-2-PYRIDYL)TRIFLIMIDE
N,N-BIS(TRIFLUOROMETHYLSULFONYL)-5-CHLORO-2-PYRIDYLAMINE
Bistrifluoromethylsulfonylaminochloropyridine
Comins
Comins'reagent
n-(5-chloro-2-pyridyl)bis(trifluoromethanesulfonyl)imide
2-[N,N-bis(trifluoromethylsulphony)amino]-5-chloropyridine
2-[N,N-BIS(TRIFLUROMETHANESULFONYL)AMINO]-5-CHLOROPYRIDINE
N-(5-chloro-2-pyridyl)bis(trifluromethanesulfonimide
2-[N,N-Bis(trifluoromethanesulfonyl)amino]-5-chloropyridine [Triflating Reagent]
2-N,N-Bis(trifluoromethanesulfonyl)aminoü-5-chloropyridine, 99%
Comins Reagent, N,N-Bis(trifluoromethylsulfonyl)-5-chloro-2-pyridylamine, 2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine
N-(5-CHLORO-2-PYRIDYL)BIS(TRILFUOROMETHANESULFONIMIDE) | [EINECS(EC#)]
629-110-2 | [Molecular Formula]
C7H3ClF6N2O4S2 | [MDL Number]
MFCD00191833 | [Molecular Weight]
392.68 | [MOL File]
145100-51-2.mol |
| Chemical Properties | Back Directory | [Appearance]
White to pale yellow crystalline solid | [Melting point ]
45-47 °C(lit.) | [Boiling point ]
77-90°C/0.2mmHg | [density ]
1.892±0.06 g/cm3(Predicted) | [storage temp. ]
Keep Cold | [solubility ]
Benzene (Slightly) | [form ]
Solid | [pka]
-7.71±0.10(Predicted) | [color ]
yellow
| [Water Solubility ]
Reacts with water. | [Sensitive ]
Moisture Sensitive | [BRN ]
5833971 | [Stability:]
Moisture Sensitive, Unstable in DMSO Solution | [InChI]
InChI=1S/C7H3ClF6N2O4S2/c8-4-1-2-5(15-3-4)16(21(17,18)6(9,10)11)22(19,20)7(12,13)14/h1-3H | [InChIKey]
TUFGVZMNGTYAQD-UHFFFAOYSA-N | [SMILES]
C(F)(F)(F)S(N(C1=NC=C(Cl)C=C1)S(C(F)(F)F)(=O)=O)(=O)=O | [CAS DataBase Reference]
145100-51-2(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P264-P271-P280-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [F ]
9 | [Hazard Note ]
Irritant | [HazardClass ]
AIR SENSITIVE, IRRITANT-HARMFUL, KEEP COLD | [HS Code ]
29350090 |
| Hazard Information | Back Directory | [Chemical Properties]
White to pale yellow crystalline solid | [Uses]
Reactant for:
Suzuki-Miyaura cross coupling
Synthesis of nicotinic acetylcholine receptor-selective ligands
Enantioselective desymmetrizing palladium catalyzed carbonylation reactions
Synthesis of high affinity niacin receptor GPR109A agonists
Preparation of heteroaromatics | [Uses]
2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine provides good yields of vinyl triflates from the corresponding ketone enolates or dienolates. It is used in the total synthesis of (-)-porantheridine and the trans decahydroquinoline alkaloid (+)-219A. It is also used as a reactant for Suzuki-Miyaura cross coupling, synthesis of nicotinic acetylcholine receptor-selective ligands, enantioselective desymmetrizing palladium catalyzed carbonylation reactions, synthesis of high affinity niacin receptor GPR109A agonists and in preparation of heteroaromatics. |
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Energy Chemical
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