ChemicalBook--->CAS DataBase List--->14516-54-2

14516-54-2

14516-54-2 Structure

14516-54-2 Structure
IdentificationBack Directory
[Name]

MANGANESE PENTACARBONYL BROMIDE
[CAS]

14516-54-2
[Synonyms]

Mn(CO)5Br
BROMOPENTACARBONYLMANGANESE
PENTACARBONYLMANGANESE BROMIDE
bromopentacarbonylmanganese(i)
pentacarbonylbromomanganese(i)
Bromopentacarbonylmanganese,98%
MANGANESE PENTACARBONYL BROMIDE
Manganesepentacarbonylbromide,min.98%
1-BROMO-2 3 5 6-TETRAFLUORO-4-(TRIFLUOR&
MANGANESE PENTACARBONYL BROMIDE MIN. 98%
Manganese, bromopentacarbonyl-, (OC-6-22)-
[EINECS(EC#)]

238-522-8
[Molecular Formula]

C5BrMnO5
[MDL Number]

MFCD00049806
[MOL File]

14516-54-2.mol
[Molecular Weight]

274.89
Chemical PropertiesBack Directory
[Appearance]

orange crystalline powder
[storage temp. ]

0-6°C
[solubility ]

Soluble in organic solvents.
[form ]

crystal
[color ]

yellow to orange
[Sensitive ]

Moisture Sensitive
[Exposure limits]

ACGIH: TWA 0.02 mg/m3; TWA 0.1 mg/m3
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
[InChI]

InChI=1S/5CO.BrH.Mn/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
[InChIKey]

OESORJHGSXJTKX-UHFFFAOYSA-M
[SMILES]

[Mn+]([Br-])(C#O)(C#O)(C#O)(C#O)C#O
Hazard InformationBack Directory
[Chemical Properties]

orange crystalline powder
[Uses]

Bromopentacarbonylmanganese(I) is used in the formation of (eta6-arene)tricarbonylmanganese(I) by reacting with arene (arene= hexamethyl benzene, 1,2,4,5-tetramethyl benzene, mesitylene, p-xylene and toluene) in the presence silver salt.
[reaction suitability]

core: manganese
reagent type: catalyst
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302+H312+H332
[Precautionary statements ]

P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22
[Safety Statements ]

36
[RIDADR ]

UN3466
[WGK Germany ]

3
[HazardClass ]

6.1
[PackingGroup ]

II
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Spectrum DetailBack Directory
[Spectrum Detail]

MANGANESE PENTACARBONYL BROMIDE(14516-54-2)Raman
MANGANESE PENTACARBONYL BROMIDE(14516-54-2)IR
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