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14220-21-4

14220-21-4 Structure

14220-21-4 Structure
IdentificationBack Directory
[Name]

RHENIUM PENTACARBONYL BROMIDE
[CAS]

14220-21-4
[Synonyms]

Re(CO)5Br
BROMOPENTACARBONYLRHENIUM
Pentacarbonylbromorhenium
Pentacarbonylrhenium bromide
bromopentacarbonylrhenium(i)
RHENIUM PENTACARBONYL BROMIDE
PENTACARBONYLBROMORHENIUM (I)
Rhenium, bromopentacarbonyl-
Rheniumpentacarbonylbromide,98%
rhenium(i) pentacarbonyl bromide
RheniuM pentacarbonyl broMide (I)
Rhenium,bromopentacarbonyl-(OC-6-22)-
Rhenium, bromopentacarbonyl-, (OC-6-22)-
[EINECS(EC#)]

238-084-8
[Molecular Formula]

C5BrO5Re
[MDL Number]

MFCD00013295
[MOL File]

14220-21-4.mol
[Molecular Weight]

406.16
Chemical PropertiesBack Directory
[Appearance]

Off-white crystalline powder
[Melting point ]

90°C (subl.)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

crystal
[color ]

off-white
[Water Solubility ]

Insoluble in water.
[Sensitive ]

Moisture Sensitive
[InChI]

1S/5CO.BrH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1
[InChIKey]

NWJBOTGGBYFKEJ-UHFFFAOYSA-M
[SMILES]

Br[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
[CAS DataBase Reference]

14220-21-4
Hazard InformationBack Directory
[Chemical Properties]

Off-white crystalline powder
[Uses]

This is used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands and also to prepare [3]-ferrocenophane complexes. The starting material for rhenium-polypyridine complexes that have potential applications in catalysis and solar energy conversion.
[reaction suitability]

core: rhenium
reagent type: catalyst
Safety DataBack Directory
[Hazard Codes ]

T
[Risk Statements ]

23/24/25-36/37/38
[Safety Statements ]

26-28-36/37/39-45
[RIDADR ]

UN 3288 6.1/PG 3
[WGK Germany ]

3
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

29310099
[Storage Class]

6.1D - Non-combustible acute toxic Cat.3
toxic hazardous materials or hazardous materials causing chronic effects
[Hazard Classifications]

Acute Tox. 3 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Spectrum DetailBack Directory
[Spectrum Detail]

RHENIUM PENTACARBONYL BROMIDE(14220-21-4)FT-IR
RHENIUM PENTACARBONYL BROMIDE(14220-21-4)Raman
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