| Identification | Back Directory | [Name]
RHENIUM PENTACARBONYL BROMIDE | [CAS]
14220-21-4 | [Synonyms]
Re(CO)5Br BROMOPENTACARBONYLRHENIUM Pentacarbonylbromorhenium Pentacarbonylrhenium bromide bromopentacarbonylrhenium(i) RHENIUM PENTACARBONYL BROMIDE PENTACARBONYLBROMORHENIUM (I) Rhenium, bromopentacarbonyl- Rheniumpentacarbonylbromide,98% rhenium(i) pentacarbonyl bromide RheniuM pentacarbonyl broMide (I) Rhenium,bromopentacarbonyl-(OC-6-22)- Rhenium, bromopentacarbonyl-, (OC-6-22)- | [EINECS(EC#)]
238-084-8 | [Molecular Formula]
C5BrO5Re | [MDL Number]
MFCD00013295 | [MOL File]
14220-21-4.mol | [Molecular Weight]
406.16 |
| Chemical Properties | Back Directory | [Appearance]
Off-white crystalline powder | [Melting point ]
90°C (subl.) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
crystal | [color ]
off-white | [Water Solubility ]
Insoluble in water. | [Sensitive ]
Moisture Sensitive | [InChI]
1S/5CO.BrH.Re/c5*1-2;;/h;;;;;1H;/q;;;;;;+1/p-1 | [InChIKey]
NWJBOTGGBYFKEJ-UHFFFAOYSA-M | [SMILES]
Br[Re].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+] | [CAS DataBase Reference]
14220-21-4 |
| Hazard Information | Back Directory | [Chemical Properties]
Off-white crystalline powder | [Uses]
This is used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands and also to prepare [3]-ferrocenophane complexes. The starting material for rhenium-polypyridine complexes that have potential applications in catalysis and solar energy conversion. | [reaction suitability]
core: rhenium reagent type: catalyst |
| Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
23/24/25-36/37/38 | [Safety Statements ]
26-28-36/37/39-45 | [RIDADR ]
UN 3288 6.1/PG 3
| [WGK Germany ]
3
| [HazardClass ]
6.1 | [PackingGroup ]
II | [HS Code ]
29310099 | [Storage Class]
6.1D - Non-combustible acute toxic Cat.3 toxic hazardous materials or hazardous materials causing chronic effects | [Hazard Classifications]
Acute Tox. 3 Oral Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
|
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Alfa Aesar
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Energy Chemical
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http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
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Alfa Chemistry
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