| Identification | More | [Name]
2-BROMO-2-PHENYLACETOPHENONE | [CAS]
1484-50-0 | [Synonyms]
2-BROMO-2-PHENYLACETOPHENONE
A-BROMODESOXY BENZOIN
AKOS BBS-00000845
ALPHA-BROMO-ALPHA-PHENYLACETOPHENONE
DESYL BROMIDE
2-bromo-1,2-diphenyl-ethanon
2-Bromo-1,2-diphenylethanone
2-bromo-1,2-diphenylethan-1-one
2-BROMO-2-PHENYLACETOPHENONE 97%
1,2-Diphenyl-2-bromoethanone
Phenyl(α-bromobenzyl) ketone
α-Bromodeoxybenzoin | [EINECS(EC#)]
216-057-1 | [Molecular Formula]
C14H11BrO | [MDL Number]
MFCD00000136 | [Molecular Weight]
275.14 | [MOL File]
1484-50-0.mol |
| Chemical Properties | Back Directory | [Appearance]
BEIGE-BROWN CRYSTALLINE POWDER | [Melting point ]
56-58 °C (lit.) | [Boiling point ]
344.8±22.0 °C(Predicted) | [density ]
1.3930 (rough estimate) | [refractive index ]
1.5130 (estimate) | [storage temp. ]
0-6°C | [solubility ]
soluble in Toluene | [form ]
Crystalline Powder | [color ]
Beige-brown | [InChI]
1S/C14H11BrO/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13H | [InChIKey]
ZFFBIQMNKOJDJE-UHFFFAOYSA-N | [SMILES]
BrC(c1ccccc1)C(=O)c2ccccc2 | [CAS DataBase Reference]
1484-50-0(CAS DataBase Reference) | [EPA Substance Registry System]
Ethanone, 2-bromo-1,2-diphenyl- (1484-50-0) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS05,GHS07 | [Signal word ]
Danger | [Hazard statements ]
H314-H335 | [Precautionary statements ]
P260-P271-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338 | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns.
R36/37:Irritating to eyes and respiratory system . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S27:Take off immediately all contaminated clothing . | [RIDADR ]
1759 | [WGK Germany ]
3 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29147000 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Eye Dam. 1
Skin Corr. 1B
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
BEIGE-BROWN CRYSTALLINE POWDER | [Uses]
Desyl bromide has been used in:
- synthesis of phosphate esters of benzoin and benzoinyl N-carbobenzyloxyglycylphenylalanate
- novel chemiluminogenic reaction for the sensitive determination of Arg-containing peptides
| [Synthesis Reference(s)]
Tetrahedron Letters, 20, p. 3653, 1979 DOI: 10.1016/S0040-4039(01)95488-7 | [General Description]
Reaction of cesium N-carbobenzyloxyglycylphenylalanate with desyl bromide in DMF has been investigated. |
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