| Identification | Back Directory | [Name]
BROMOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) | [CAS]
14973-89-8 | [Synonyms]
orange crystal
Einecs 239-050-5
BROMOTRIS(TRIPHENYLP
99.95%(metalsbasis),Rh10.1%min
Tris(triphenylphosphine)bromide
bromotris(triphenylphosphine)rhodium
BROMO-TRIS-(TRIPHENYLPHOSPHINO)RHODIUM
BROMOTRIS(TRIPHENYLPHOSPHINE)RHODIUM(I)
rhodium(I) tris(triphenylphosphine) bromide
TRIS(TRIPHENYLPHOSPHINE)RHODIUM(I) BROMI DE
Bromotris(triphenylphosphine)rhodium(I), 99.95% (metals basis)
Bromotris(Triphenylphosphine)Rhodium(I) (Metals Basis), Rh 10.1% Min
Bromotris(triphenylphosphine)rhodium(I), 99.95% (metals basis), Rh 10.1% min | [EINECS(EC#)]
239-050-5 | [Molecular Formula]
C54H45BrP3Rh | [MDL Number]
MFCD00009828 | [MOL File]
14973-89-8.mol | [Molecular Weight]
969.67 |
| Chemical Properties | Back Directory | [Appearance]
orange crystals | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [solubility ]
Soluble in chlorinated solvents | [form ]
Crystalline | [Sensitive ]
Air sensitive | [Exposure limits]
ACGIH: TWA 0.01 mg/m3; TWA 1 mg/m3
NIOSH: IDLH 2 mg/m3; IDLH 100 mg/m3; TWA 0.001 mg/m3; TWA 0.1 mg/m3 |
| Questions And Answer | Back Directory | [Reaction]
- Rhodium-catalyzed regio- and stereoselective addition of diphenylphosphine oxide to alkynes.
- Rhodium- catalyzed hydrophosphinylation.
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