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1502-03-0

1502-03-0 Structure

1502-03-0 Structure
IdentificationMore
[Name]

CYCLODODECYLAMINE
[CAS]

1502-03-0
[Synonyms]

AMINOCYCLODODECANE
CYCLODODECYLAMINE
TIMTEC-BB SBB003726
Cyclododecanamine
1-Cyclododecanamine
[EINECS(EC#)]

216-118-2
[Molecular Formula]

C12H25N
[MDL Number]

MFCD00003718
[Molecular Weight]

183.33
[MOL File]

1502-03-0.mol
Chemical PropertiesBack Directory
[Appearance]

CLEAR SLIGHTLY YELLOW LIQUID AFTER MELTING
[Melting point ]

27-29 °C(lit.)
[Boiling point ]

122-124 °C7 mm Hg(lit.)
[density ]

0.9093 (rough estimate)
[refractive index ]

1.487-1.489
[Fp ]

250 °F
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[pka]

10.98±0.20(Predicted)
[CAS DataBase Reference]

1502-03-0(CAS DataBase Reference)
[EPA Substance Registry System]

Cyclododecanamine (1502-03-0)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 3259 8/PG 3
[WGK Germany ]

3
[TSCA ]

TSCA listed
Hazard InformationBack Directory
[Chemical Properties]

CLEAR SLIGHTLY YELLOW LIQUID AFTER MELTING
[Production Methods]

Cyclododecylamine is produced by reduction of cyclododecanone oxime with sodium and an alcohol, by catalytic reduction of nitrocyclododecane with hydrogen, by Ritter reaction of cyclododecene with hydrocyanic acid, or by hydrogenation of cyclododecanone under amination conditions. The reaction of cyclododecylamine with propylene oxide leads to a product that can undergo cyclization to give the fungicide Dodemorph (BASF). The compound behaves chemically as a primary amine.
[Purification Methods]

It can be purified via the hydrochloride salt m 274-275o (from EtOH) or the picrate m 232-234o, and the free base is distilled preferably at water-pump vacuum [Prelog et al. Helv Chim Acta 33 365 1950].
Spectrum DetailBack Directory
[Spectrum Detail]

CYCLODODECYLAMINE(1502-03-0)MS
CYCLODODECYLAMINE(1502-03-0)1HNMR
CYCLODODECYLAMINE(1502-03-0)IR1
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

1502-03-0(sigmaaldrich)
[TCI AMERICA]

Cyclododecylamine,>98.0%(GC)(1502-03-0)
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