| Identification | Back Directory | [Name]
DIALLYL CARBONATE | [CAS]
15022-08-9 | [Synonyms]
Allyl carbonate
DIALLYL CARBONATE
Carbonic acid diallyl
Diallyl carbonate 99%
bis(prop-2-enyl) carbonate
Carbonic acid, diallyl ester
carbonicacid,di-2-propenylester
Carbonic acid O,O-diallyl ester
Carbonic acid, di-2-propenyl ester
Carbonic acid,di-2-propen-1-yl ester | [EINECS(EC#)]
239-106-9 | [Molecular Formula]
C7H10O3 | [MDL Number]
MFCD00008645 | [MOL File]
15022-08-9.mol | [Molecular Weight]
142.15 |
| Chemical Properties | Back Directory | [Melting point ]
25°C | [Boiling point ]
95-97 °C60 mm Hg(lit.) | [density ]
0.991 g/mL at 25 °C(lit.) | [refractive index ]
n20/D 1.428(lit.) | [Fp ]
138 °F | [storage temp. ]
2-8°C | [form ]
liquid | [Appearance]
Colorless to light yellow Liquid | [InChI]
1S/C7H10O3/c1-3-5-9-7(8)10-6-4-2/h3-4H,1-2,5-6H2 | [InChIKey]
JKJWYKGYGWOAHT-UHFFFAOYSA-N | [SMILES]
C=CCOC(=O)OCC=C | [EPA Substance Registry System]
Carbonic acid, di-2-propen-1-yl ester (15022-08-9) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-36/37/39 | [RIDADR ]
UN 3272 3/PG 3 | [WGK Germany ]
3 | [TSCA ]
TSCA listed | [REACH Registrations]
Active | [HazardClass ]
3.2 | [PackingGroup ]
III | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Uses]
Transesterification of diallyl carbonate with glycerol in the presence of a catalyst (Pd/PPh3), generates glycerol carbonate. | [General Description]
Diallyl carbonate is an acrylating agent. Allyl carbonates are widely employed in Tsuji-Trost allylation, generating carbanion, boronate, phosphide, amide and alkoxide, nucleophiles in situ and improving reaction rates over allyl acetate. Allyl carbonates are also of considerable interest for the intramolecular decarboxylative assymetric couplings. |
|
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Sigma-Aldrich
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Rhawn Reagent
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http://www.rhawn.cn |
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