ChemicalBook--->CAS DataBase List--->1572-52-7

1572-52-7

1572-52-7 Structure

1572-52-7 Structure
IdentificationMore
[Name]

2-Methyleneglutaronitrile
[CAS]

1572-52-7
[Synonyms]

2,4-DICYANO-1-BUTENE
2-METHYLENEGLUTARONITRILE
2-methylenepentanedinitrile
2,4-Dicyanobutene-1
2-Methyleneglutarodinitrile
2-methylene-pentanedinitril
alpha-Methyleneglutarodinitrile
alpha-Methyleneglutaronitrile
Glutaronitrile, 2-methylene-
Methylene glutaronitrile
Pentanedinitrile, 2-methylene-
2-METHYLENEGLUTARONITRILE 95%
acrylonitrile dimer
3-Butene-1,3-dicarbonitrile
[EINECS(EC#)]

216-391-8
[Molecular Formula]

C6H6N2
[MDL Number]

MFCD00001869
[Molecular Weight]

106.13
[MOL File]

1572-52-7.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless liquid.Slightly soluble in water; insoluble in aliphatic andalicyclic hydrocarbons, soluble in aromatic hydro-carbons and polar organic solvents.
[Melting point ]

−9.6 °C(lit.)
[Boiling point ]

254 °C(lit.)
[density ]

0.976 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.456(lit.)
[Fp ]

>230 °F
[storage temp. ]

Sealed in dry,Room Temperature
[Uses]

Vinyl monomer for polymerization and copoly-merization, intermediate in making fibers and phar-maceuticals.
[CAS DataBase Reference]

1572-52-7(CAS DataBase Reference)
[NIST Chemistry Reference]

Pentanedinitrile, 2-methylene-(1572-52-7)
[EPA Substance Registry System]

1572-52-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S36:Wear suitable protective clothing .
[RIDADR ]

UN 3276 6.1/PG 3
[WGK Germany ]

3
[TSCA ]

TSCA listed
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

2926907090
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

DBDCB-->1,3,5-Pentanetricarbonitrile-->1,4-Dicyano-2-butene
Hazard InformationBack Directory
[Description]

2-Methyleneglutaronitrile [1572-52-7], acrylonitrile dimer, 2,4-dicyano-1-butene, 2- methylenepentanedinitrile, NCC2H4C (=CH2) CN, is a colorless liquid slightly miscible with water, ethanol, acetone and benzene, immiscible with hexane.
[Chemical Properties]

Colorless liquid.Slightly soluble in water; insoluble in aliphatic andalicyclic hydrocarbons, soluble in aromatic hydro-carbons and polar organic solvents.
[Synthesis Reference(s)]

Tetrahedron Letters, 28, p. 4591, 1987 DOI: 10.1016/S0040-4039(00)96573-0
[Synthesis]

2-Methyleneglutaronitrile is obtained by dimerization of acrylonitrile in the presence of a metal halide and a tertiary amine. Its hydrogenation yields 2-methylglutaronitrile, which in turn can be converted into 3-methylpyridine.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Methyleneglutaronitrile(1572-52-7)MS
2-Methyleneglutaronitrile(1572-52-7)1HNMR
2-Methyleneglutaronitrile(1572-52-7)13CNMR
2-Methyleneglutaronitrile(1572-52-7)IR1
2-Methyleneglutaronitrile(1572-52-7)IR2
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

1572-52-7(sigmaaldrich)
[TCI AMERICA]

2-Methyleneglutaronitrile,>98.0%(GC)(1572-52-7)
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