ChemicalBook--->CAS DataBase List--->15804-19-0

15804-19-0

15804-19-0 Structure

15804-19-0 Structure
IdentificationMore
[Name]

2,3-DIHYDROXYQUINOXALINE
[CAS]

15804-19-0
[Synonyms]

2,3-DIHYDROXYPHENPIAZINE
2,3-DIHYDROXYQUINOXALINE
2,3-QUINOXALINEDIOL
QUINOXALINE-2,3-DIOL
TIMTEC-BB SBB000138
1,4-Dihydro-2,3-quinoxalinedione
1,4-dihydro-3-quinoxalinedione
2,3(1h,4h)-quinoxalinedione
2,3-dihydroxy-quinoxalin
2,3-Quinoxalinedione, 1,4-dihydro-
2,3-Quinoxalinedione,1,4-dihydro-
Quinoxaline, 2,3-dihydroxy-
USAF ek-6232
usafek-6232
2,3-Dihydroxyquinoxaline, 99+%
quinoxaline-2,3(1H,4H)-dione
2,3-dihydroquinoxaline
2,3(1H,4H)-Quinoxalinedione, 2,3-Quinoxalinediol
[EINECS(EC#)]

239-901-0
[Molecular Formula]

C8H6N2O2
[MDL Number]

MFCD00006723
[Molecular Weight]

162.15
[MOL File]

15804-19-0.mol
Chemical PropertiesBack Directory
[Appearance]

off-white powder
[Melting point ]

>300 °C (lit.)
[Boiling point ]

288.82°C (rough estimate)
[density ]

1.3264 (rough estimate)
[refractive index ]

1.5770 (estimate)
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

powder to crystaline
[pka]

10.66±0.20(Predicted)
[color ]

White to Orange to Green
[BRN ]

136884
[InChI]

InChI=1S/C8H6N2O2/c11-7-8(12)10-6-4-2-1-3-5(6)9-7/h1-4H,(H,9,11)(H,10,12)
[InChIKey]

ABJFBJGGLJVMAQ-UHFFFAOYSA-N
[SMILES]

N1C2=C(C=CC=C2)NC(=O)C1=O
[CAS DataBase Reference]

15804-19-0(CAS DataBase Reference)
[EPA Substance Registry System]

2,3-Quinoxalinedione, 1,4-dihydro- (15804-19-0)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

22-37/38-41
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[RTECS ]

VD2100000
[TSCA ]

Yes
[HS Code ]

29339900
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Dam. 1
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Chemical Properties]

off-white powder
[Uses]

2,3-Dihydroxyquinoxaline is a fluorescent reagent and it can be used for the determination of trace Pb(II) in vinegar.
[Application]

2,3-Dihydroxyquinoxaline can be used:
(1)  Basic chemical studies to determine the low-temperature x-ray molecular structure, reciprocal isomerism and spectroscopic properties of 2,3-Dihydroxyquinoxaline[1].
(2) Quinoline-5-carboxamide derivatives (Vq-Vu) and (VIa-Vu) were prepared by using methyl 2,3-diaminobenzoate as raw material[2].
[General Description]

2,3-Dihydroxyquinoxaline(dhq) undergoes electrophilic substitution reaction with sulphuric acid solution and potassium nitrate to form 2,3-dihydroxy-6-nitroquinoxaline. It reacts with Ru3(CO)12 in DMSO to give the Ru(CO)2(dhq)(DMSO) complex.
[References]

[1] SAIED M. SOLIMAN; Morsy A M A Y; J?rg Albering. Low temperature X-ray molecular structure, tautomerism and spectral properties of 2,3-dihydroxyquinoxaline[J]. Journal of Molecular Structure, 2013. DOI:10.1016/j.molstruc.2013.09.005.
[2] KEESARI SRINIVAS. Synthesis, Characterization, and Antibacterial Activity of Novel 2,3-Dihydroxyquinoxaline-5-сarboxamide Derivatives[J]. Russian Journal of Bioorganic Chemistry, 2023. DOI:10.1134/S106816202305014X.
Spectrum DetailBack Directory
[Spectrum Detail]

2,3-DIHYDROXYQUINOXALINE(15804-19-0)MS
2,3-DIHYDROXYQUINOXALINE(15804-19-0)1HNMR
2,3-DIHYDROXYQUINOXALINE(15804-19-0)13CNMR
2,3-DIHYDROXYQUINOXALINE(15804-19-0)IR1
2,3-DIHYDROXYQUINOXALINE(15804-19-0)IR2
2,3-DIHYDROXYQUINOXALINE(15804-19-0)Raman
2,3-DIHYDROXYQUINOXALINE(15804-19-0)ESR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2,3-Dihydroxyquinoxaline, 99+%(15804-19-0)
[Alfa Aesar]

2,3-Dihydroxyquinoxaline, 98%(15804-19-0)
[Sigma Aldrich]

15804-19-0(sigmaaldrich)
[TCI AMERICA]

2,3-Dihydroxyquinoxaline,>98.0%(T)(15804-19-0)
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