ChemicalBook--->CAS DataBase List--->1623-88-7

1623-88-7

1623-88-7 Structure

1623-88-7 Structure
IdentificationBack Directory
[Name]

5-Chloromethylfurfural
[CAS]

1623-88-7
[Synonyms]

5-(CHLOROMETHYL)FURFURAL
5-(ChloroMethyl)-2-furfural
2-ForMyl-5-chloroMethylfuran
5-(chloromethyl)-2-furaldehyde
5-(ChloroMethyl)furfuraldehyde
5-(Chloromethyl)furan-2-carbaldehyde
2-Furancarboxaldehyde, 5-(chloromethyl)-
2-[5-(chloromethyl)-2-furanyl]acetaldehyde
[EINECS(EC#)]

216-608-6
[Molecular Formula]

C6H5ClO2
[MDL Number]

MFCD02181084
[MOL File]

1623-88-7.mol
[Molecular Weight]

144.56
Chemical PropertiesBack Directory
[Melting point ]

37 °C
[Boiling point ]

137-138 °C(Press: 5 Torr)
[density ]

1.295±0.06 g/cm3(Predicted)
[storage temp. ]

Inert atmosphere,Store in freezer, under -20°C
[solubility ]

Chloroform (Slightly), Ethyl Acetate (Slightly)
[form ]

Dark Brown to Black Oil to Semi-Solid
[Stability:]

Moisture Sensitive
[InChI]

InChI=1S/C6H5ClO2/c7-3-5-1-2-6(4-8)9-5/h1-2,4H,3H2
[InChIKey]

KAZRCBVXUOCTIO-UHFFFAOYSA-N
[SMILES]

O1C(CCl)=CC=C1C=O
[EPA Substance Registry System]

2-Furancarboxyaldehyde, 5-(chloromethyl)- (1623-88-7)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H314
[Precautionary statements ]

P260-P264-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P321-P363-P405-P501
[HS Code ]

2932190090
Hazard InformationBack Directory
[Chemical Properties]

Dark Brown Oil
[Uses]

5-(Chloromethyl)furfural is a lipid oxidation product derived from soybean phospholipids. It is a biofuel precursor in the co-processing of carbohydrates and lipids in oil crops for production of hybrid biodiesel.
[Uses]

A lipid oxidation product derived from soybean phospholipids. It is a biofuel precursor in the co-processing of carbohydrates and lipids in oil crops for production of hybrid biodiesel.
[Application]

5-Chloromethylfurfural is a biofuel that can be made from the reaction of hydrochloric acid and furfural. It is used as a feedstock for the production of 5-hydroxymethylfurfural, which is an important intermediate in the synthesis of many other chemicals. 5-Chloromethylfurfural has been isolated at a yield of 57% from reactions between furfural and chlorine gas. The use of solid catalysts have improved this yield to 68%. It has high chemical stability and can withstand temperatures up to 200°C without decomposition. It also reacts with fatty acids to form amides.
[Synthesis Reference(s)]

Synthesis, p. 541, 1992 DOI: 10.1055/s-1992-26158
[General Description]

5-(Chloromethyl) Furfural (CMF) is a potential chemical building block for replacing petroleum-derived chemicals derived from lignocellulosic feedstocks. It is gaining traction as a more practical alternative to 5-(hydroxymethyl)furfural (HMF).
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